Figure 6.

Applications of TRIS‐XRPD to follow ball‐milling syntheses. I) Mechanochemical formation of MOF‐74, characterized by TRIS‐XRPD. The time‐resolved diffractograms (left) show a complex interconversion of intermediates prior to formation of the final MOF‐74 phase. Figure modified from Ref. [69] with permission. Copyright 2021 American Chemical Society. II) Mechanochemical synthesis of ZIF‐8, as followed by TRIS‐XRD (left) and Raman spectroscopy (right). Yellow: reactants, orange: reactants and product ZIF‐ 8, red: product ZIF‐8, blue: product ZIF‐8 with not yet perfectly arranged 2‐methylimidazolate molecules within the crystal structure. Figures modified from Ref. [56] with permission. Copyright 2015, Wiley‐VCH.