Table 3.

Isomerisation of Z‐olefins catalysed by rhodium complexes.

Entry[a]	Substrate		Cat.	t	T	Yield[b]
	R	R’		[h]	[°C]	[%]
1	Ph	Ph	2	24	80	100
2	Ph	Me	2	12	80	77
3	Me	Et	2	24	120	75
4	Me	t Bu	2	6	80	100
5	Ph	Ph	5	24	80	0
6	Ph	Ph	6	24	80	0
7	Ph	Ph	7	24	80	<10
8	Ph	Ph	8	24	80	0
9	Ph	Ph	9	24	80	0
10	Ph	Ph	10	24	80	0

[a] Reaction conditions: alkene (0.03 mmol), catalyst (0.003 mmol; 10 mol%), C₆D₆ (0.5 mL). [b] Yields determined by ¹H NMR spectroscopy using C₆Me₆ as internal standard.