表4.
实际水样中7种苯氧羧酸类除草剂的分析结果(n=3)
| Analyte | Spiked/(μg/L) | Tap water | Reservoir water | |||||
|---|---|---|---|---|---|---|---|---|
| Found/(μg/L) | Recovery/% | RSD/% | Found/(μg/L) | Recovery/% | RSD/% | |||
| 4-CPA | 0 | ND | ND | |||||
| 0.01 | 0.008 | 80 | 3.5 | 0.007 | 72 | 4.1 | ||
| 0.05 | 0.043 | 86 | 0.6 | 0.046 | 92 | 2.6 | ||
| 0.2 | 0.178 | 89 | 8.3 | 0.171 | 86 | 4.9 | ||
| PB | 0 | ND | ND | |||||
| 0.01 | 0.009 | 90 | 5.5 | 0.008 | 80 | 2.4 | ||
| 0.05 | 0.044 | 88 | 2.3 | 0.045 | 90 | 4.1 | ||
| 0.2 | 0.182 | 91 | 2.5 | 0.179 | 90 | 6.5 | ||
| 2,4-D | 0 | ND | ND | |||||
| 0.01 | 0.008 | 80 | 11.3 | 0.009 | 90 | 7.6 | ||
| 0.05 | 0.042 | 84 | 3.1 | 0.047 | 94 | 2.9 | ||
| 0.2 | 0.179 | 90 | 2.3 | 0.168 | 84 | 1.5 | ||
| MCPA | 0 | ND | ND | |||||
| 0.01 | 0.008 | 80 | 9.5 | 0.009 | 90 | 5.4 | ||
| 0.05 | 0.043 | 86 | 2.8 | 0.043 | 86 | 3.3 | ||
| 0.2 | 0.167 | 84 | 4.4 | 0.158 | 79 | 4.2 | ||
| 2,4,5-T | 0 | ND | ND | |||||
| 0.01 | 0.008 | 80 | 8.1 | 0.008 | 80 | 11.5 | ||
| 0.05 | 0.046 | 92 | 2.4 | 0.045 | 90 | 3.2 | ||
| 0.2 | 0.175 | 88 | 4.6 | 0.178 | 89 | 5.1 | ||
| 2,4-DB` | 0 | ND | ND | |||||
| 0.01 | 0.010 | 102 | 6.2 | 0.011 | 110 | 7.5 | ||
| 0.05 | 0.045 | 90 | 6.4 | 0.063 | 126 | 10.4 | ||
| 0.2 | 0.166 | 83 | 9.6 | 0.214 | 107 | 6.6 | ||
| 2,4,5-TP | 0 | ND | 0.004 | |||||
| 0.01 | 0.009 | 90 | 0.7 | 0.013 | 90 | 11.0 | ||
| 0.05 | 0.047 | 94 | 8.1 | 0.047 | 86 | 9.1 | ||
| 0.2 | 0.176 | 88 | 3.3 | 0.153 | 75 | 6.0 | ||
ND: not detected.