Table 3. Hydrogen-bond Geometry (Å, deg)a.
| D–H···A | D–H | H···A | D···A | ∠(D–H···A)° |
|---|---|---|---|---|
| N2–H2···O1 | 0.88 | 2.11 | 2.683 (2) | 122 |
| N2–H2···F5i | 0.88 | 2.34 | 3.067 (2) | 140 |
| C11–H11···O1ii | 0.95 | 2.44 | 3.345 (2) | 159 |
| C24–H24···F7iii | 0.95 | 2.51 | 3.356 (2) | 148 |
| C15–H15C···F7iv | 0.98 | 2.62 | 3.570 (3) | 164 |
| C31–H31···F8v | 0.95 | 2.48 | 3.412 (2) | 168 |
| C–H···π | C–H | H···π | C··· π | ∠(C–H··· π)° |
| C21–H21···Cg1 | 0.95 | 2.95 | 3.508 (2) | 119 |
| C15–H15B···Cg2vi | 0.98 | 2.73 | 3.624 (2) | 152 |
a
Symmetry codes: (i) −x + 2, −y + 2, −z + 1; (ii) −x + 2, −y + 1, −z + 1; (iii) −x + 1, −y + 2, −z + 1; (iv) x, y–1, z; (v) −x, −y + 1, −z; (vi) 1 – x, 1 – y, 1 – z. Cg1 and Cg2 are the centroid of phenyl rings (C22–C27) and (C29–C34), respectively.