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. 2022 Aug 10;61(33):13149–13164. doi: 10.1021/acs.inorgchem.2c01902

Table 5. Kinetic Constant for the Reaction of Complex 3 with Alcohols at 333 Ka.

entry alcohol 106kobs/s–1
1 MeOH 8.12 ± 0.07
2 EtOH 11.6 ± 0.1
3 nPrOH 4.0 ± 0.2
4 BnOH 24.9 ± 0.5
5 iPrOH 1.12 ± 0.04
6 CH3OD 1.56 ± 0.03
7 CD3OH 1.0 ± 0.1
a

See the SI for experimental details.