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. 2022 Aug 10;61(33):13149–13164. doi: 10.1021/acs.inorgchem.2c01902

Table 6. Kinetic Constants for the H/D Exchange at 313 Ka.

entry R–OD 105kobs/s–1
1 D–OD 9.5 ± 0.2
2 CH3–OD 28.2 ± 0.6
3 CD3–OD 16.9 ± 0.2
4 Et–OD 7.73 ± 0.08
5 iPr–OD 1.92 ± 0.04
a

See the SI for experimental details.