Table 1.

Summary of studies on the synthesis of MIL-101(Cr) by different synthetic methods.

Method	Synthesis Conditions			Textural Properties				Ref.
	Medium	Time	Temp (°C)	Yield (%)	SBET (m2 g−1)	Vpore (cm3 g−1)	Particle Size (nm)
Hydrothermal	H2O/HF	8 h	220	50	4100	2.02	/	[18]
	H2O/HNO3	8 h	220	78	3841	1.72	720–2120	[26]
	H2O/NaOH	8 h	220	47	4065	2.01	87	[27]
	H2O/HNO3	8 h	220	81	3187	1.65	1336
	H2O/HOAc	8 h	220	53	2894	1.38	141
	H2O/HCl	8 h	220	/	3090	1.64	200–1200	[28]
	H2O/HCOOH	8 h	210	/	2618	1.36	100–150	[29]
	H2O/TMAOH	24 h	160	/	3197	1.73	/	[30]
	H2O/CH3COONa	12 h	200	40	1710	0.80	0.5–1.4	[31]
	H2O/CH3COOH	8 h	200	55	2927	1.77	1.3–2.1
	H2O/CH3COOLi	12 h	220	/	3401	1.83	480	[32]
	H2O/CH3COOK	12 h	220	/	3398	1.79	240
Solvothermal	H2O/HF	96 h	220	/	3780	1.74	/	[33]
Mixed-solvothermal	DMF/H2O	24 h	160	83.3	2453.1	1.16	200	[34]
Microwave (MW)	H2O/HF	1 h	220	/	3054	2.01	70–100	[35]
MW-assisted solvo/hydrothermal	H2O	30 min	220	/	2667	1.37	100–110	[36]
MV	H2O/HF	40 min	210	/	3900	2.3	70–90	[37]
	H2O	15 min	210	36	3071	1.51	200	[38]
	H2O	1 h	210	38	3196	1.55	200
Electric heating (CE)	H2O	6 h	210	31	2735	1.43	800
	H2O	24 h	210	42	3160	1.54	400
MV	H2O	10 min	210	29	1710.1	1.28	100	[39]
CE	H2O	12 h	210	35	2284.7	1.76	400
MV/CE	H2O	4 min/12 h	210	41	1664.9	1.17	135
MV/CE	H2O	4 min/3 h	210	37	1747.6	1.35	155
expanded graphite (EG)	H2O/HF	2 h	220	43	3751	1.8	400	[40]
cetyltrimethylammonium bromide (CTAB)	H2O/HF	8 h	220	/	638	0.51	3.25	[41]
CTAB	H2O/HF	8 h	220	/	1560	/	3.91	[42]
CTAB	NaAc	12 h	220	/	1144	/	3.47
CTAB	H2O/HF	8 h	220	/	846	/	120–250	[43]