Table 1.

Optimised MS/MS parameters for the analysed compounds, including precursor ions, product ions, declustering potential (DP), collision energy (CE), and collision cell exit potential (CXP).

Mycotoxins	Precursor ion (m/z)	Product ion (m/z)	DP (V)	CE (eV)	CXP
Regulated mycotoxins
Aflatoxin B1	313.061	285.1	121	33	14
	313.061	241.1	121	53	14
Aflatoxin B2	315.074	287.2	141	37	14
	315.074	259.1	141	41	14
Aflatoxin G1	329.055	243.2	131	37	18
	329.055	311.1	131	31	16
Aflatoxin G2	331.057	313	106	35	16
	331.057	245.2	106	41	14
Deoxynivalenol	297.097	249.1	91	21	20
	297.097	203.2	91	21	20
Fumonisin B1	722.316	334.4	100	53	10
	722.316	704.3	100	41	38
HT-2 toxin	447.169	345.1	131	27	18
	447.169	285.2	131	29	14
T2 toxin	489.175	387.2	151	31	36
	489.175	245.2	151	35	12
Ochratoxin A	404.092	239	111	33	12
	404.092	358.1	111	21	18
Zearalenone	319.114	301.1	81	15	16
	319.114	283.1	81	17	14
Emerging mycotoxins
Alternariol	256.957	213	−125	−34	−19
	256.957	215	−125	−36	−17
Beauvericin	801.287	784.3	141	27	14
	801.287	244.1	141	43	12
Enniatin A	699.386	682.4	100	27	24
	699.386	210.2	100	39	22
Enniatin A1	685.36	668.5	100	27	12
	685.36	210.1	100	39	10
Enniatin B	657.319	640.3	100	27	22
	657.319	196.1	100	39	10
Enniatin B1	671.317	654.4	6	27	22
	671.317	196.1	6	41	22
Stachybotrylactam	386.184	178	191	47	22
	386.184	150.2	191	57	14
Sterigmatocystin	325.023	310.1	121	35	16
	325.023	281.6	121	41	14
Masked mycotoxin
3-acetyl deoxynivalenol	337.1	59.2	−110	−28	−13
	337.1	255.2	−110	−52	−9
15-acetyl deoxynivalenol	339.1	321.3	81	13	18
	339.1	261.1	81	17	14
Deoxynivalenol-3-glucoside	517.3	427.1	−70	−30	−11
	517.3	59.1	−70	−85	−7
Alpha-Zearalenol	319.2	160.1	−105	−44	−13
	319.2	130.1	−105	−50	−20
Beta-Zearalenol	319.2	160	−105	−44	−13
	319.2	130	−105	−50	−20
Zearalenone-14-glucoside	479.2	317.1	−145	−24	−15
	479.2	175	−145	−54	−11
Zearalenone-14-glucoside	479.12	317.105	−140	−30	−21
	479.12	149	−140	−50	−15