1H NMR spectra of extracts for resistant wheat Sumai 3 inoculated with (a) ddH2O, (b) Fg WT 5035, (c) Fg TPS1− mutant, and (d) Fg TPS2− mutant for 96 h. The region δ 5.31–9.21 was vertically expanded 8 times. Keys: 1, isoleucine (Ile); 2, leucine (Leu); 3, valine (Val); 4, threonine (Thr); 5, alanine (Ala); 6, arginine (Arg); 7, methionine (Met); 8, γ-aminobutyrate (GABA); 9, glutamate (Glu); 10, glutamine (Gln); 11, aspartate (Asp); 12, asparagine (Asn); 13, phenylalanine (Phe); 14, tryptophan (Trp); 15, tyrosine (Tyr); 16, histidine (His); 17, sucrose; 18, α-glucose; 19, β-glucose; 20, raffinose; 21, fructose; 22, myo-inositol; 23, acetate; 24, pyruvate; 25, succinate; 26, lactate; 27, formate; 28, fumarate; 29, citrate; 30, α-ketoglutarate (α-KG); 31, malate; 32, choline; 33, phosphocholine (PC); 34, glycine betaine (GB); 35, ethanolamine (EA); 36, dimethylamine; 37, adenosine; 38, uridine; 39, guanosine; 40, hypoxanthine; 41, inosine; 42, deoxy adenosine monophosphate (dAMP); 43, p-hydorxy cinnamic acid; 44, chlorogenic acid; 45, thymidine.