Gas-sensing properties of representative ordered macroporous metal oxide materials. Here, the selectivity value is defined with the sensing response ratio of the target gas to the reference gas, and the stability is evaluated with the declining proportion (%) of sensing response within a specified period (month).
Samples | Template | Pore size (nm) | Temp. (°C) | Target gas | Conc. (ppm) | Gas response | Selectivity value | Stability (%/month) | Res./Rec. time (s) | Ref. |
---|---|---|---|---|---|---|---|---|---|---|
Close-network ZnO | PS spheres | 400 | 25 | NO2 | 50 | 27.5 | 213.75 to ethanol | — | 35/65 | 48 |
Bowl-like ZnO | PS spheres | 280 | 25 | NO2 | 50 | 4.5 | 2.25 to ethanol | — | 125/210 | |
Ordered SnO2 | PS spheres | 200 | 350 | Ethanol | 3 | 3.9 | 1.625 to acetone | −11.8/6 | 0.73/— | 91 |
Porous LaFeO3 | PS spheres | 500 | 450 | Ethanol | 5 | 15 | 3.21 to HCHO | — | 6/5 | 97 |
2D hollow SnO2 | PS spheres | ∼1000 | 300 | HCHO | 0.5 | 23 | 3.67 to CH4 | — | 1.8/5.4 | 84 |
2D porous ZnO | PS spheres | 420 | 300 | Acetone | 10 | 17 | 1.7 to ethanol | −5/6 | —/— | 85 |
Ordered SnO2 | PS spheres | ∼500 | 350 | Ethanol | 0.1 | 1.24 | — | — | 1/1 | 92 |
Bowl-like SnO2 | PS spheres | 500 | 300 | Ethanol | 1 | 4.3 | — | −48/2 | 2/2 | 90 |
α-Fe2O3 IO film | PS spheres | 500 | 400 | NO2 | 5 | — | — | −4.2/1 | 12/— | 98 |
Embossed TiO2 | PS beads | 1000 | 250 | Ethanol | 500 | 219 | 4.38 to CO | — | 10/— | 83 |
Monolayer Mg–NiO | PS spheres | 700 | 325 | Ethanol | 100 | 10.4 | 6.5 to benzene | −10.6/1 | 13/19 | 95 |
Au–SnO2: 5% In | PMMA spheres | 250 | 275 | Ethanol | 100 | 292 | 41.71 to MeOH | — | 7/12 | 108 |
Hollow Pt–SnO2 | PMMA spheres | 800 | 250 | H2 | 250 | 4.08 | — | — | 31/— | 86 |
Ethanol-aged SnO2 | PS spheres | 500 | 400 | Sarin | 0.006 | 40 | 1.2 to DMMP | — | —/— | 99 |
Porous In2O3/CuO | PS spheres | 450 | 250 | Ethanol | 1000 | 9.6 | 5.33 to CO | — | 48 | 94 |
2D Au/In2O3 | PS spheres | 500 | 350 | Ethanol | 5 | 1640.2 | 282.79 to HCHO | — | —/— | 103 |
3D IO SnO2 | PMMA spheres | 400 | 215 | HCHO | 100 | 629 | 104.83 to ethanol | −6/2 | 12/58 | 71 |
3D IO WO3 | PMMA spheres | 422.2 | 370 | Acetone | 5 | 7 | 3.89 to MeOH | — | 10/34 | 76 |
3DOM Tm–In2O3 | PMMA spheres | 200 | 175 | Ethanol | 100 | 122 | 7.63 to acetone | −2.4/1 | 9/13 | 118 |
3DOM Sn–NiO | PMMA spheres | 200 | 225 | HCHO | 100 | 145 | 96.7 to NO2 | −2.1/1 | 30/160 | 119 |
3DOM In–ZnO | PMMA spheres | 150 | 250 | Ethanol | 100 | 88 | 1.83 to acetone | — | 25/10 | 113 |
3DOM Li–WO3 | PMMA spheres | ∼330 | 25 | NO2 | 0.5 | 55 | 42.31 to NH3 | −9.1/1 | 100/100 | 120 |
3DOM Li/K–WO3 | PMMA spheres | 200 | 25 | NO2 | 0.5 | 4.5 | 4.09 to NH3 | — | 15/10 | 138 |
3DOM Pd/In2O3 | PMMA spheres | 210 | 25 | NO2 | 0.5 | 980 | 196 to NH3 | 0/1 | 270/286 | 123 |
3D IO Au/In2O3 | PMMA spheres | 420 | 340 | Acetone | 5 | 42.4 | 10.6 to ethanol | — | —/— | 117 |
3DOM Au/In2O3 | PMMA spheres | 140 | 230 | Ethanol | 100 | 205 | 6.83 to MeOH | — | 15/21 | 78 |
3DOM Pd/WO3 | PMMA spheres | ∼330 | 130 | H2 | 50 | 382 | 191 to HCHO | −1/1 | 10/50 | 115 |
3D IO ZnO–In2O3 | PS spheres | 170 | 300 | Acetone | 100 | 35.2 | 25.14 to benzene | −9.1/1 | 1/— | 129 |
3D IO In2O3–CuO | PMMA spheres | 410 | 370 | Acetone | 50 | 39.1 | 9.5 to ethanol | −2.8/1.3 | 8/20 | 124 |
3DOM ZnO–CuO | PMMA spheres | 282 | 310 | Acetone | 1 | 1.8 | 1.53 to toluene | −11/1 | —/— | 114 |
3D IO PdO@In2O3 | PS spheres | 636.6 | 250 | Acetone | 100 | 50.9 | 11.31 to C6H6 | −11.6/1 | —/26 | 139 |
3DOM/M LaFeO3 | PMMA spheres | 191/8–20 | 190 | Methanol | 100 | 96 | 2.44 to ethanol | — | 25/23 | 140 |
3DOM/M-SnO2 | PS spheres | 100/20/3 | 400 | Ethanol | 5 | 316.5 | 3.50 to ethanol | — | 1/416 | 141 |
3DOM/M-ZnO | PMMA spheres | 600/25 | 260 | Acetone | 100 | 137 | — | — | 13/50 | 130 |
3DOM/M In2O3–ZnO | PS spheres | 80/4 | 25 | NO2 | 5 | 54.3 | 6.9 to MeOH | — | 586/188 | 128 |
3DOM/M Pt–SnO2 | Electrosprayed spheres | 300/17 | 250 | H2S | 1 | 10.8 | — | — | 192.4/76.5 | 142 |
3DOM/M ZnO–Fe3O4 | PMMA spheres | 350/30 | 485 | Acetone | 50 | 47 | 8.44 to C5H12 | — | —/— | 137 |