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Fig. 1. Schematic illustration of biomineralization-inspired methods for selective synthesis of discotic and calamitic liquid crystals through crystallization control of poly(acrylic acid) (PAA)-stabilized amorphous calcium carbonate (ACC) precursors by changing the concentration ratio of methanol to water in the crystallization solution. The purple spheres in the nanodisk and the yellow tetrahedrons in the nanorod show vaterite and calcite nanocrystallites, respectively. The red curved lines represent PAA molecules.