XPS ratios of sp2, hydroxyl (C–O), carbonyl (C O) and carboxyl (C–O–O) groups, and the magnetic nature of GO.
Material | Synthesis | (C C) sp2 (area%) | (C–O) (%) | (C O)*/(C–O–O) (%) | sp2/sp3 | Magnetic nature | Moment (emu gm−1) | Spin density (spins per g) | Ref. |
---|---|---|---|---|---|---|---|---|---|
GO | Brodie method | 73.7 | 17.3 | 9* | 2.8 | SG | — | 22 and 156 | |
GO (heated for 24 h, 180 °C) | Brodie method | 86.7 | 10.2 | 3.1* | 6.52 | PM | — | 23 and 156 | |
NaOH treated GO | Brodie method | 55.8 | 32 | 12.2* | 1.26 | PM | — | 23 and 156 | |
GO | Brodie or and Hummer’s method | 23.32 | 45.33 | 1.48/10.94* | 1.23 | PM + DM | 0.75 | 20.2 × 1018 | 22 and 157 |
GO | Pyrolysis of silk cocoon | — | — | — | — | (FM) | 0.005 | — | 24 |
BGO | Brodie method | — | — | — | — | (AFM) + (PM) | — | 2 × 1018 | 25 |
HGO | Hummer’s method | — | — | — | — | (AFM) + (PM) | — | 2 × 1019 | 25 |
Monolayer GO quantum dots | Oxidative cutting | 59.5 | 2.5 | 0.5*/30.5 | — | PM + FM | 0.159 | 5.7 × 1018 | 26 |
GO | Modified Hummer’s method | — | — | — | — | SG | — | — | 27 |