TABLE 2.

Chemical components structurally identified from S. nigrum.

No	Chemical constituents	Molecular formula	CAS	Extracts	References
Steroidal saponins
1	Diosgenin	C27H42O3	512-04-9	MeOH	Gao et al. (2021)
					Tsuyoshi et al. (2003)
2	Degalactotigonin	C50H82O22	39941-51-0	EtOH	Wang (2007)
3	Stigmasterol	C29H48O	83-48-7	EtOH	Zhao (2010)
4	Pterosterone	C27H44O7	18089-44-6	EtOH	Zhao (2010)
5	12-keto-porrigenin	C27H42O5	189014-45-7	EtOH	Zhao (2010)
6	28-O-β- d-glucopyranosyl betulinic acid 3β-O-β-D glucopyranoside	C42H68O13		EtOH	Yang (2014)
7	β-daucosterol	C35H60O6	474-58-8	EtOH	Yang (2014)
8	(25R)-5α-furost-3β, 22α-diol-12-one-26-carboxylicacid-3-O-β-D-glucopyranosy-(1→4)-[O-β-d-glucopyranosyl-(1→2)]-O- β-d-glucopyranosyl-(1→4)-O-β-d-galactopyranoside	C47H76O20		EtOH	Li (2010b)
9	Tigogenin3-O-β-d-glucopyranosyl-(1→2)-[O-β-d-xyloyranosyl-(1→3)]-O-β-d-glucopyranosyl-(1→4)-O-β-d-galactopyranoside	C52H86O21		EtOH	Li (2010b)
10	Uttroside A	C57H96O28	82003-86-9	EtOH	He et al. (2015), Zhou (2006)
11	Uttroside B	C56H94O28	88048-09-3	EtOH	He et al. (2015), Zhou (2006)
12	(22α, 25R)-26-O-(β-d-glucopyranosyl)-22-methoxy-furost-Δ5-3β, 26-diol-3-O-β-d-glucopyranosyl	C57H94O28		EtOH	He et al. (2015), Zhou (2006)
	-(1→2)-O-[β-d-xylopyranosyl-(1→3)]-O-β-d-glucopyranosyl-(1→4)-O-β-d-galactopyranoside
13	(22α, 25R)-26-O-(β-d-glucopyranosyl)-22-hydroxy-furost-Δ5-3β, 26-diol-3-O-β-d-glucopyranosyl-(1→2)-O-[β-d-xylopyranosyl-(1→3)]-O-β-d-glucopyranosyl-(1→4)-O-β-d-galactopyranoside	C57H92O28		EtOH	He et al. (2015), Zhou (2006)
14	(5α, 22α, 25R)-26-O-(β-d-glucopyranosyl)-22-methoxy-furostan-3β, 26-diol-3-β-d-glucopyranosyl-(1→2)-O-[β-d-glucopyranosyl-(1→3)]- O-β-d-glucopyranosyl-(1→4)-O-β-d-galactopyranoside	C58H98O29	108886-03-9	EtOH	He et al. (2015), Zhou (2006)
15	(5α, 22α, 25R)-26-O-(β-d-glucopyranosyl-22-hydroxy-furost-3β,26-diol-3-β-d-glucopyranosyl-(1→2)-O-[β-d-glucopyranosyl-(1→3)]-O-β-d-glucopyranosyl-(1→4)-O-β-d-galactopyranoside	C57H96O29		EtOH	He et al. (2015), Zhou (2006)
16	Solanigroside I	C62H104O31		EtOH	He et al. (2015), Zhou (2006)
17	Solanigroside J	C61H102O31	1354759-80-0	EtOH	He et al. (2015), Zhou (2006)
18	Solanigroside K	C57H94O28		EtOH	He et al. (2015), Zhou (2006)
19	Solanigroside L	C57H92O28		EtOH	He et al. (2015), Zhou (2006)
20	Solanigroside M	C57H92O28		EtOH	He et al. (2015), Zhou (2006)
21	Solanigroside N	C57H94O28		EtOH	He et al. (2015), Zhou (2006)
22	Solanigroside R	C50H84O23		EtOH	He et al. (2015), Zhou (2006), Tai et al. (2018)
23	Solanigroside S	C50H86O23		EtOH	He et al. (2015), Zhou (2006)
24	Solanigroside T	C45H84O22		EtOH	He et al. (2015), Zhou (2006)
25	Hypoglaucin H	C39H60O15	50773-43-8	EtOH	Zhou (2006)
26	5α-pregn-16-en-3β-ol-20-one-lycotetraoside	C44H70O21		EtOH	He et al. (2015), Zhou (2006)
27	Solanigroside A	C49H78O24	1029362-42-2	EtOH	He et al. (2015), Zhou (2006)
28	Solanigroside B	C45H72O22	1029362-44-4	EtOH	He et al. (2015), Zhou (2006)
29	(5α, 20S)-3β, 16β-dihydroxy pregn-22-carboxylic acid (22, 16)-lactone-3-O-β-d-glucopyranosyl-(1→2)-O-[β-D-xylopy ranosyl-(1→3)]-O-β-d- glucopyranosyl-(1→4)-O-β-d-galactopyranoside	C45H72O22		EtOH	He et al. (2015), Zhou (2006)
30	Solanigroside U	C50H80O25		EtOH	He et al. (2015), Zhou (2006)
31	Solanigroside V	C50H80O25		EtOH	He et al. (2015), Zhou (2006)
32	Solanigroside W	C45H70O22		EtOH	He et al. (2015), Zhou (2006)
33	Solanigroside X	C45H72O23		EtOH	He et al. (2015), Zhou (2006)
34	Nigrumnin I	C55H90O25		EtOH	He et al. (2015), Zhou (2006)
35	Solanigroside C	C51H82O26	905914-27-4	EtOH	He et al. (2015), Zhou (2006)
36	Solanigroside D	C55H88O27	905914-28-5	EtOH	He et al. (2015), Zhou (2006)
37	Solanigroside E	C55H88O28	905914-29-6	EtOH	He et al. (2015), Zhou (2006)
38	Solanigroside F	C56H92O28	905914-30-9	EtOH	He et al. (2015), Zhou (2006)
39	Solanigroside G	C50H82O23	905914-31-0	EtOH	He et al. (2015), Zhou (2006)
40	Solanigroside O	C51H86O23		EtOH	He et al. (2015), Zhou (2006)
41	Nigroside A	C56H94O29	386747-86-0	EtOH	He et al. (2015), Zhou (2006)
42	Tigogenin/(25R)-5α-spirostan-3β-ol	C27H44O3		EtOH	Wu (2011)
43	(25R)-26-O-β-d-glucopyranosyl-cholest-5(6)-en-3β, 26-diol-16,22-dione-3-O-α-l-rhamnopyranosyl	C51H86NO23		MeOH	Xiang et al. (2018)
	-(1→2)-[β-d-glucopyranosyl-(1→3)]-β-d-galactopyranoside
44	(25R)-26-O-β-d-glucopyranosyl-cholest-5(6)-en-3β, 26-diol-16,22-dione-3-O-α-l-rhamnopyranosyl	C45H76NO18		MeOH	Xiang et al. (2018)
	-(1→4)-β-d-glucopyranoside
45	(25S)-26-O-β-d-glucopyranosyl-cholest-5(6)-en-3β, 26-diol-16, 22-dione-3-O-α-l-rhamnopyranosyl	C57H96NO27		MeOH	Xiang et al. (2018)
	-(1→2)-[α-Lrhamnopyranosyl-(1→4)]-[β-d-glucopyranosyl-(1→6)]-β-d-glucopyranoside
46	(25R)-26-O-β-d-glucopyranosyl-(1→2)-β-d-glucopyranosyl-cholest-5(6)-en-3β, 26-diol-16, 22-dione-3-O-α-Lrhamnopyranosyl-(1→2)-[α-l-rhamnopyranosyl-(1→4)]-[β-d-glucopyranosyl-(1→6)]-β-d-glucopyranoside	C63H106NO32		MeOH	Xiang et al. (2018)
47	(25S)-26-O-β-d-glucopyranosyl-cholest-5(6)-en-3β, 26-diol-16, 22-dione-3-O-β-d-glucopyranosyl	C57H96NO28		MeOH	Xiang et al. (2018)
	-(1→6)-β-d-glucopyranosyl-(1→3)-[α-l-rhamnopyranosyl-(1→2)]-β-d-galactopyranoside
48	(25R)-26-O-β-d-glucopyranosyl-(1→2)-β-d-glucopyranosyl-cholest-5(6)-en-3β, 26-diol-16, 22-dione-3-O-α-l-rhamnopyranosyl-(1→2)-[β-d-glucopyranosyl-(1→3)]-β-d-galactopyranoside	C57H96NO28		MeOH	Xiang et al. (2018)
49	(25R)-26-O-β-d-glucopyranosyl-cholest-5α-3β, 26-diol-16, 22-dione-3-O-β-d-glucopyranosyl-(1→2)-[β-d-glucopyranosyl-(1→3)]-β-d-glucopyranosyl-(1→4)-β-d-galactopyranoside	C57H98NO29		MeOH	Xiang et al. (2018)
50	Stigmast-5, 22-dien-3β-ol	C29H48O		EtOH	Sharma et al. (2012)
51	Inunigroside A	C50H82O23	1427934-51-7	MeOH	Ohho et al. (2012)
52	Solanigroside Y1	C51H82O26	2098576-14-6	MeOH	Wang et al. (2017)
53	Solanigroside Y2	C51H82O26	2098576-15-7	MeOH	Wang et al. (2017)
54	Solanigroside Y3	C51H80O26	2098576-16-8	MeOH	Wang et al. (2017)
55	Solanigroside Y4	C45H70O21	2098576-17-9	MeOH	Wang et al. (2017)
56	Solanigroside Y5	C57H94O28	2098576-18-0	MeOH	Wang et al. (2017)
57	Solanigroside Y6	C57H94O27	2098576-19-1	MeOH	Wang et al. (2017)
58	Solanigroside Y7	C63H106O34	2098576-20-4	MeOH	Wang et al. (2017)
59	Solanigroside Y8	C62H104O33	2098576-21-5	MeOH	Wang et al. (2017)
60	Solanigroside Y9	C62H104O33	2098576-22-6	MeOH	Wang et al. (2017)
61	(25R)-26-O-β-D-glucopyranosylfurost-5(6)-ene-3β, 22α, 26-triol-3-O-β-d-glucopyranosyl-(1→2)-[β-d-glucopyranosyl-(1→3)]-β-d-glucopyranosyl-(1→4)-β-d-galactopyranoside	C57H96O30		MeOH	Wang et al. (2017)
62	(25R)-26-O-β-Dglucopyranosylfurost-5(6)-ene-3β, 22α, 26-triol-3-O-α-l-rhamnopyranosyl-(1→2)-[α-l-rhamnopyranosyl-(1→4)]-β-d-glucopyranoside	C57H92O25		MeOH	Wang et al. (2017)
63	(25R)-26-O-β-D-glucopyranosylfurost-5(6)-ene-16α-methoxy-3β, 26-diol-3-O-α-l-rhamnopyranosyl	C39H60O16		MeOH	Wang et al. (2017)
	-(1→2)-[α-l-rhamnopyranosyl-(1→4)]-β-d-glucopyranoside
64	(25R)-26-O-β-d-glucopyranosyl-5α-furost-3β, 22α, 26-triol-3-O-β-d-glucopyranosyl-(1→2)-[β-d-glucopyranosyl-(1→3)]-β-d-glucopyranosyl-(1→4)-β-d-galactopyranoside	C57H94O30		MeOH	Wang et al. (2017)
65	(25S)-26-O-β-d-glucopyranosyl-5α-furost-3β, 22α, 26-triol-3-O-β-d-glucopyranosyl-(1→2)-[β-d-glucopyranosyl-(1→3)]-β-d-glucopyranosyl-(1→4)-β-d-galactopyranoside	C57H94O30		MeOH	Wang et al. (2017)
66	(25R)-26-O-β-Dglucopyranosyl-22α-methoxy-5α-furost-3β, 26-diol-3-O-β-d-glucopyranosyl-(1→2)-[β-d-glucopyranosyl-(1→3)]-β-d-glucopyranosyl-(1→4)-β-d-galactopyranoside	C57H96O30		MeOH	Wang et al. (2017)
67	Uttroside B ((25R)-26-O-β-d-glucopyranosyl-5α-furost-3β, 22α, 26-triol-3-O-β-d-glucopyranosyl	C56H94O28	88048-09-3	MeOH	Wang et al. (2017)
	-(1→2)-[β-d-xylopyranosyl-(1→3)]-β-d-glucopyranosyl-(1→4)-β-d-galactopyranoside)
68	β-sitosterol	C29H50O	83-46-5	EtOH	Yang (2014)
69	β-carotene glycosides	C35H58O6		EtOH	Yang (2014)
70	Tigogenin	C27H44O3	77-60-1	EtOH	He et al. (2015), Zhou (2006)
71	Uttronin A	C50H82O22	39941-51-0	EtOH	He et al. (2015), Zhou (2006)
72	Uttronin B	C39H62O12	84955-03-3	EtOH	He et al. (2015), Zhou (2006)
73	Dumoside	C40H62O16	221526-58-5	EtOH	He et al. (2015), Zhou (2006)
74	Nigrumnin II	C55H88O27		EtOH	He et al. (2015), Zhou (2006)
75	Solanigroside H	C51H82O22	905914-32-1	EtOH	He et al. (2015), Zhou (2006)
76	Cholesterol	C27H46O	57-88-5	EtOH	Geng et al. (2020)
Alkaloids
77	β1-solasonine	C39H63NO11	73069-18-8	EtOH	He et al. (2015), Zhou (2006)
78	β2-solasonine	C39H63NO12	73069-19-9	EtOH	He et al. (2015), Zhou (2006)
79	Solamargine	C45H73NO15	20311-51-7	EtOH	He et al. (2015), Zhou (2006), Wang (2007)
80	β2-solamargine	C39H63NO11	32449-98-2	EtOH	He et al. (2015), Zhou (2006) Wang (2007)
81	Solanigroside P	C39H63NO12	1446029-15-7	EtOH	He et al. (2015), Zhou (2006)
82	Solanigroside Q	C45H69NO15		EtOH	He et al. (2015), Zhou (2006), Tai et al. (2018)
83	(3β, 12β, 22α, 25R)-3, 12-dihydroxy-spirosol-5-en-27-oic acid	C27H41NO5		EtOH	He et al. (2015), Zhou (2006)
84	Solaoiacid	C44H83NO19		H2O	Shi et al. (2019)
85	(25R)-22αN-4-nor-spirosol-5(6)-en-3β-ol-6-al-3-O-l-rhamnopyranosyl-(1→2)-[α-l-rhamnopyranosyl-(1→4)]-β-d-glucopyranoside	C45H72NO16		MeOH	Xiang et al. (2019)
86	(25R)-22αN-spirosol-5(6)-en-3β-ol-7-oxo-3-O-l-rhamnopyranosyl-(1→2)-[α-l-rhamnopyranosyl-(1→4)]-β-d-glucopyranoside	C45H72NO16		MeOH	Xiang et al. (2019)
87	(25R)-22αN-spirosol-4(5)-en-3β-ol-6-oxo-3-O-α-Lrhamnopyranosyl-(1→2)-[α-l-rhamnopyranosyl	C45H72NO16		MeOH	Xiang et al. (2019)
	-(1→4)]-β-d-glucopyranoside
88	Solasodine	C27H43NO2	126-17-0	EtOH	He et al. (2015), Zhou (2006)
89	N-methylsolasodine	C28H45NO2	7604-92-4	EtOH	He et al. (2015), Zhou (2006)
90	Tomatidenol	C27H43NO2	546-40-7	EtOH	He et al. (2015), Zhou (2006)
91	Solanocapsine	C27H46N2O2	639-86-1	EtOH	Liu et al. (2020), Zhou (2006)
92	Solanaviol	C27H43NO3	74131-93-4	EtOH	He et al. (2015), Zhou (2006)
93	Solasodine-3-O-β-d-glucopyranoside	C33H53NO7		EtOH	Chang et al. (2017)
94	12β-hydroxysolasodine β-solatrioside	C45H73NO17		EtOH	He et al. (2015), Zhou (2006)
95	12β, 27-dihydroxy solasodine β-chacotrioside	C45H73NO17		EtOH	He et al. (2015), Zhou (2006)
96	23-O-acetyl-12β-hydroxysolasodine	C29H45NO15	117803-97-1	EtOH	He et al. (2015), Zhou (2006)
97	(3β, 22α, 25R)-spirosol-5-en-3yl-O-α-l-Rhamanopyranosyl-(1-2)-[O-β-d-glucopyranosyl(1–3)]-O-β-d-galactopyranoside	C39H85NO15	101009-59-0	EtOH	Yang (2014)
98	15α-hydroxysolasodine	C27H43NO3	10009-88-8	EtOH	Wu (2011)
99	α-Solanine	C45H73NO15	20562-02-1	EtOH	Huang et al. (2020)
100	Solasonine	C45H73NO16	19121-58-5	EtOH	He et al. (2015), Zhou (2006)
101	Leptinine I	C45H73NO15		EtOH	Gao et al. (2021)
102	(7R, 8S)-1-(4-hydroxy-3-methoxyphenyl)-2-{4-{2-[N-2-(4-hydroxyphenyl)ethyl]Carbamoylehenyl	C28H32NO8		EtOH	Li et al. (2019)
	-2-methoxyphenoxyl}}-1, 3-propanodiolnamed
103	(7S, 8R)-1-(4-hydroxy-3-methoxyphenyl)-2-{4-{2-[N-2-(4-hydroxyphenyl)ethyl]Carbamoylehenyl	C28H32NO8		EtOH	Li et al. (2019)
	-2-methoxyphenoxyl}}-1, 3-propanodiolnamed
104	(7R, 8R)-1-(4-hydroxy-3-methoxyphenyl)-2-{4-{2-[N-2-(4-hydroxyphenyl)ethyl]Carbamoylehenyl	C28H32NO8		EtOH	Li et al. (2019)
	-2-methoxyphenoxyl}}-1, 3-propanodiolnamed
105	(7S, 8S)-1-(4-hydroxy-3-methoxyphenyl)-2-{4-{2-[N-2-(4-hydroxyphenyl)ethyl]Carbamoylehenyl-2-methoxyphenoxyl}}-1, 3-propanodiolnamed	C28H32NO8		EtOH	Li et al. (2019)
106	7′S, 8′R-7-hydroxy-1-(4-hydroxy-3-methoxyphenyl)-N2, N3-bis(4-hydroxyphenethyl)-6-methoxy	C36H37N2O8		EtOH	Li et al. (2019)
	-1, 2-dihydronaphthalene-2, 3-dicarboxamide
107	7′R, 8′S-7-hydroxy-1-(4-hydroxy-3-methoxyphenyl)-N2, N3-bis(4-hydroxyphenethyl)-6-methoxy	C36H37N2O8		EtOH	Li et al. (2019)
	-1, 2-dihydronaphthalene-2, 3-dicarboxamide
108	7′R, 8′S-7-(4-hydroxy-3, 5-dimethoxyphenyl)-3′-hydroxymethyl-1′-[N-7″-(4″-hydrxyphenyl)ethyl] carbamoylethenyl-3′-methoxybenzodihydrofuran	C29H31NO8		EtOH	Li et al. (2019)
109	7′S, 8′R-7-(4-hydroxy-3, 5-dimethoxyphenyl)-3′-hydroxymethyl-1′-[N-7″-(4″-hydrxyphenyl)ethyl] carbamoylethenyl-3′-methoxybenzodihydrofuran	C29H31NO8		EtOH	Li et al. (2019)
110	(7′R, 8′R)-2-(4-Hydroxy-3-methoxyphenyl)-3-[N-2-(4-hydroxyphenyl)ethyl]carbamoyl-5-[N-2-(4-hydroxyphenyl)ethyl]carbamoylethenyl-7-methoxybenzodihydrofurn	C36H36N2O8		EtOH	Li et al. (2019)
111	(7′S, 8′S)-2-(4-Hydroxy-3-methoxyphenyl)-3-[N-2-(4-hydroxyphenyl)ethyl]carbamoyl-5-[N-2-(4-hydroxyphenyl)ethyl]carbamoylethenyl-7-methoxybenzodihydrofurn	C36H36N2O8		EtOH	Li et al. (2019)
112	Cannabisin F	C36H36N2O8	163136-19-4	EtOH	Li et al. (2019)
113	Adenine	C5H5N5	73-24-5	MeOH	Gao et al. (2021)
114	Pyroglutamic acid	C5H7NO3	98-79-3	MeOH	Gao et al. (2021)
115	Nicotinic acid	C6H5NO2	59-67-6	MeOH	Gao et al. (2021)
116	9-aminononane-1,3,9-tricarboxylic acid	C12H21NO6		MeOH	Gao et al. (2021)
117	Glutarylcarnitine	C12H21NO6	102636-82-8	MeOH	Gao et al. (2021)
118	(6S)-3-((1H-imidazol-4-yl)methyl)-6-amino-1, 4-diazocane-2, 5, 8-trione	C10H13N5O3		MeOH	Gao et al. (2021)
119	3-Indoleacrylic acid	C11H9NO2		MeOH	Gao et al. (2021)
120	6-Hydroxypurine	C5H4N4O	68-94-0	MeOH	Gao et al. (2021)
121	Uridine	C9H12N2O6	58-96-8	MeOH	Gao et al. (2021)
122	Ethyl 4-glycylbenzoate	C11H13NO3		MeOH	Gao et al. (2021)
123	Adenosine	C10H13N5O4	58-61-7	MeOH	Gao et al. (2021), Wang (2007)
124	Dihydrocapsaicin	C18H29NO3	19408-84-5	MeOH	Gao et al. (2021)
125	Choline	C5H14NO	62-49-7	MeOH	Gao et al. (2021)
126	Betaine	C5H11NO2	107-43-7	MeOH	Gao et al. (2021)
127	Allantoin	C4H6N4O3	97-59-6	MeOH	Gao et al. (2021)
128	Uracil	C4H4N2O2	66-22-8	MeOH	Gao et al. (2021)
129	Trigonelline	C7H7NO2	535-83-1	MeOH	Gao et al. (2021)
130	(2-acetoxyethyl)trimethylammonium	C7H16NO2 +		MeOH	Gao et al. (2021)
131	Glycyl-l-leucine	C8H16N2O3		MeOH	Gao et al. (2021)
132	GABA	C4H9NO2	56-12-2	MeOH	Gao et al. (2021)
133	FMoc-Asn(Trt)-OPfp	C44H31F5N2O5		MeOH	Gao et al. (2021)
Phenylpropanoids
134	Trans-4-Hydroxycinnamic acid	C9H8O3	501-98-4	EtOH	Liu et al. (2019b)
135	Cis-4-Hydroxycinnamic acid	C9H8O3	4501-31-9	EtOH	Liu Z et al. (2019)
136	Ethyl 3, 4-dihydroxycinnaMate	C11H12O4	102-37-4	EtOH	Liu et al. (2019a)
137	Cis-caffeic acid ethyl ester	C11H12O4	74257-25-3	EtOH	Liu et al. (2019b)
138	Trans ferulic acid	C10H10O4	537-98-4	EtOH	Liu Z et al. (2019)
139	Cis-ferulic acid	C10H10O4	1014-83-1	EtOH	Liu et al. (2019a)
140	Caffeic acid	C9H8O4	331-39-5	MeOH	Gao et al. (2021)
141	4-(4-hydroxyphenyl)-2-methylenebutyrolactone	C11H10O3		EtOH	Liu et al. (2019b)
142	Chlorogenic acid	C16H18O9	327-97-9	MeOH	Gao et al. (2021)
143	3-caffeoylquinic acid methyl ester	C17H20O9	123483-19-2	MeOH	Xiang et al. (2019)
144	Scopoletin	C10H8O4	92-61-5	EtOH	Zhao (2010), Wang et al. (2007), Wang (2007)
145	(−)-5′-methoxyisolariciresinol-3α-O-β-d-glucopyranoside	C27H36O12		MeOH	Xiang et al. (2019)
146	(+)-isolariciresinol-3α-O-β-d-glucopyranoside	C26H34O11		MeOH	Xiang et al. (2019)
147	Cinnacassoside A	C26H36O12	1691248-24-4	MeOH	Xiang et al. (2019)
148	Pinoresinol	C20H22O6	81446-29-9	EtOH	Zhao (2010)
149	Pinoresinol-4-O-β-d-glucopyranoside	C26H32O11	69251-96-3	EtOH	Wang et al. (2007), Wang (2007)
150	Syringaresinol	C22H26O8	487-35-4	EtOH	Zhao (2010)
151	Syringaresinol-4-O-β-d-glucopyranoside	C28H36O13	137038-13-2	EtOH	Wang et al. (2007), Wang (2007)
152	Medioresinol	C21H24O7	40957-99-1	EtOH	Zhao (2010)
153	Acanthoside D	C34H46O18	573-44-4	MeOH	Xiang et al. (2019)
154	(+)-medioresonol-di-O-β-d-glucopyranoside	C33H44O17		MeOH	Xiang et al. (2019)
Flavonoids
155	Quercetin	C15H10O7	117-39-5	EtOH	Yang (2014)
156	Quercitrin	C21H20O11	522-12-3	EtOH	Yang (2014)
157	Isoquercitrin	C21H20O12	21637-25-2	EtOH	Yang (2014)
158	Quercetin-3-O-β-d-glucopyranosyl(1-2)-β-d-glucopyranoside	C27H30O17		EtOH	Yang (2014)
159	Quercetin-3-O-β-d-galactopyranosyl-(1→6)-β-d-glucopyranoside	C28H32O17		MeOH	Xiang et al. (2019)
160	Quercetin-3-gentiobioside	C27H30O17	7431-83-6	EtOH	Wu (2011)
161	Quercetin-3-O-α-l-rhaopyranosyl(1→4)-O-β-d-glucopyranosyl-(1→6)-O-β-d-glucopyranoside	C28H32O17		EtOH	Li (2010b)
162	6-Hydroxyluteolin 7-sophoroside	C27H30O17		MeOH	Gao et al. (2021)
163	Kaempferol	C15H10O6	520-18-3	EtOH	Liu Z et al. (2019)
164	(8-hydroxy-3′-β-d-galactosyl-isoflavone)-2′-8″-(4‴-hydroxy-flavone)-biflavone	C36H28O11		EtOAc	Sabudak et al. (2017)
165	2′, 3′, 5-trihydroxy-5″-methoxy-3″-O- α-glucosyl-3-4‴-O-biflavone	C36H30O15		EtOAc	Sabudak et al. (2017)
Benzoic acids
166	Gallic acid	C7H6O5	149-91-7	MeOH	Gao et al. (2021)
167	2, 4-Dihydroxybenzoic acid	C7H6O4	89-86-1	MeOH	Gao et al. (2021)
168	Protocatechuic acid	C7H6O4	99-50-3	EtOH	Zhao (2010)
169	Vanillic acid	C8H8O4	121-34-6	EtOH	Zhao (2010)
170	4-Hydroxybenzoic acid	C7H6O3	99-96-7	EtOH	Liu et al. (2019a)
171	Salicylic acid	C7H6O3	69-72-7	EtOH	Liu et al. (2019b)
172	2, 5-Dihydroxybenzoic acid	C7H6O4	490-79-9	MeOH	Gao et al. (2021)
Other compounds
173	Galacturonic acid	C6H10O7	14982-50-4	MeOH	Gao et al. (2021)
174	Pyruvic acid	C3H4O3	127-17-3	MeOH	Gao et al. (2021)
175	Formic acid	CH2O2	64-18-6	MeOH	Gao et al. (2021)
176	Succinic acid	C4H6O4	110-15-6	MeOH	Gao et al. (2021)
177	Fumaric acid	C4H4O4	110-17-8	MeOH	Gao et al. (2021)
178	Ursolic acid	C30H48O3	77-52-1	EtOH	Zhao (2010)
179	Linolenic acid	C18H30O2	463-40-1	MeOH	Gao et al. (2021)
180	Oleic acid	C18H34O2	112-80-1	EtOH	Wang (2007)
181	Linoleic acid	C18H32O2	60-33-3	EtOH	Wang (2007)
182	Palmitic acid	C16H32O2	57-10-3	EtOH	Wang (2007)
183	1-monolinolenin	C21H36O4	75685-85-7	EtOH	Zhao (2010)
184	Lignoceric acid	C24H48O2	557-59-5	EtOH	Zhao (2010)
185	(E)-docosyl-3-(4-hydroxy-3-methoxyphenyl)acrylate	C32H54O4		EtOH	Zhao (2010)
186	α-carotene	C40H56	432-70-2	EtOH	Wu (2011)
187	β-carotene	C40H56	7235-40-7	EtOH	Wu (2011)
188	Xanthophyll	C40H56O2	127-40-2	EtOH	Wu (2011)