Table 3.
mDES from Table1 | Time days | Conversion (%) | Control reactionsa | ||||||
---|---|---|---|---|---|---|---|---|---|
Ketone 1 | Lactone 2 | Ketone 3 | Lactone 4 | Ketone 5 | Lactone 6 | Ketone 1,3,5 | Lactone 2,4,6 | ||
7 | 1 | 59.8 | 40.1 | 73.2 | 26.8 | 88.6 | 11.4 | 100 | 0 |
2 | 11.1 | 88.9 | 9.9 | 90.1 | 47.6 | 52.4 | 100 | 0 | |
3 | 1.0 | 99.0 | 0.9 | 99.1 | 7.9 | 92.1 | 100 | 0 | |
6 | 0 | 100 | 0 | 100 | 0 | 100 | 100 | 0 | |
8 | 1 | 26.0 | 74.0 | 41.7 | 58.3 | 68.1 | 31.9 | 100 | 0 |
2 | 2.0 | 98.0 | 8.7 | 91.3 | 15.8 | 84.2 | 100 | 0 | |
3 | 1.9 | 98.1 | 5.0 | 95.0 | 9.3 | 90.7 | 100 | 0 | |
6 | 1.3 | 98.7 | 4.7 | 95.3 | 7.0 | 93.0 | 100 | 0 | |
9 | 1 | 25.7 | 74.3 | 65.1 | 34.9 | 60.2 | 39.8 | 100 | 0 |
2 | 18.3 | 81.7 | 36.0 | 64.0 | 31.4 | 68.6 | 100 | 0 | |
3 | 16.5 | 83.5 | 22.8 | 77.2 | 29.1 | 70.9 | 100 | 0 | |
6 | 12.1 | 87.9 | 19.1 | 80.9 | 28.0 | 72.0 | 100 | 0 | |
10 | 1 | 97.4 | 2.6 | 95.4 | 4.5 | 95.0 | 5.0 | 100 | 0 |
2 | 94.0 | 6.0 | 94.9 | 5.1 | 95.8 | 4.2 | 100 | 0 | |
3 | 94.0 | 6.0 | 92.5 | 7.5 | 95.5 | 4.5 | 100 | 0 | |
6 | 76.4 | 23.6 | 91.9 | 8.1 | 94.4 | 5.6 | 100 | 0 | |
11 | 1 | 10.7 | 89.3 | 35.2 | 64.8 | 49.1 | 50.9 | 100 | 0 |
2 | 9.4 | 90.6 | 16.2 | 83.8 | 33.8 | 66.2 | 100 | 0 | |
3 | 6.8 | 93.2 | 14.6 | 85.4 | 29.4 | 70.6 | 100 | 0 | |
6 | 3.6 | 96.4 | 7.4 | 92.6 | 21.3 | 78.7 | 100 | 0 |
aControl reactions were carried out by excluding respectively lipase, octanoic acid and oxidant from the reaction mixture.