The 13C NMR data for 1–7.
Position | 1a | 2a | 3b | 4a | 5a | 6a | 7a |
---|---|---|---|---|---|---|---|
δ C | δ C | δ C | δ C | δ C | δ C | δ C | |
1 | 39.4, CH2 | 43.3, CH2 | 43.1, CH2 | 35.8, CH2 | 79.9, CH | 39.6, CH2 | 43.8, CH2 |
2 | 27.8, CH2 | 28.0, CH2 | 28.4, CH2 | 27.0, CH2 | 35.8, CH2 | 28.0, CH2 | 28.2, CH2 |
3 | 54.2, CH | 53.9, CH | 53.5, CH | 52.1, CH | 49.0, CH | 54.0, CH | 54.0, CH |
4 | 55.2, CH | 51.5, CH | 56.1, CH | 44.3, CH | 55.8, CH | 49.1, CH | 53.1, CH |
5 | 48.8, C | 43.4, C | 42.3, C | 56.3, C | 45.4, C | 47.5, C | 43.9, C |
6 | 81.5, CH | 52.5, CH2 | 58.1, CH2 | 208.0, C | 40.8, CH2 | 87.3, CH | 51.5, CH2 |
7 | 131.7, CH | 70.6, CH | 218.6, C | 127.1, C | 123.5, CH | 204.3, C | 74.1, CH |
8 | 136.6, C | 141.4, C | 48.4, CH | 152.2, C | 140.6, C | 134.9, C | 155.0, C |
9 | 36.9, CH2 | 126.3, CH | 27.1, CH2 | 35.5, CH2 | 37.0, CH2 | 143.4, CH | 34.0, CH2 |
10 | 24.1, CH2 | 27.8, CH2 | 18.9, CH3 | 22.8, CH2 | 24.3, CH2 | 29.9, CH2 | 27.7, CH2 |
11 | 27.1, CH3 | 23.5, CH3 | 74.1, C | 28.3, CH3 | 27.4, CH3 | 21.9, CH3 | 113.1, CH2 |
12 | 75.0, C | 74.8, C | 21.2, CH3 | 73.9, C | 74.8, C | 74.3, C | 74.6, C |
13 | 14.4, CH3 | 18.9, CH3 | 11.1, CH3 | 20.1, CH3 | 13.5, CH3 | 14.0, CH3 | 19.7, CH3 |
14 | 32.3, CH3 | 32.4, CH3 | 32.1, CH3 | 32.5, CH3 | 32.1, CH3 | 32.9, CH3 | 32.0, CH3 |
15 | 26.8, CH3 | 27.2, CH3 | 27.3, CH3 | 27.2, CH3 | 27.1, CH3 | 27.1, CH3 | 27.7, CH3 |
13C (150 MHz) NMR data in CD3OD.
13C (150 MHz) NMR data in CDCl3.