Kinetics models for IC adsorption by Bi2O3 doped MgO.
Kinetics model | Kinetic equation | Parameter | MgOBi0 | MgOBi1 | MgOBi2 | MgOBi3 |
---|---|---|---|---|---|---|
PFO57 | ln(qe − qt) = ln qe − k1t | q e (mg g−1) | 49.02 | 63.79 | 100.43 | 44.05 |
K 1 (min−1) | 0.20 | 0.22 | 0.23 | 0.19 | ||
R 2 | 0.97 | 0.96 | 0.96 | 0.98 | ||
PSO57 | q m (exp) (mg g−1) | 64.50 | 68.80 | 101.71 | 59.80 | |
q m (cal) (mg g−1) | 70.07 | 76.04 | 110.74 | 67.70 | ||
K 2 (g mg−1 min−1) × 104 | 7.17 | 5.17 | 3.04 | 4.81 | ||
h 0 (mg g−1 min−1) | 3.52 | 2.98 | 3.72 | 2.19 | ||
t 1/2 (min) | 19.72 | 25.43 | 29.70 | 30.70 | ||
R 2 | 0.99 | 0.99 | 0.99 | 0.99 | ||
IPD58 | q t = kdift1/2 + C | K dif1 (mg g−1 min1/2) | 6.22 | 6.60 | 7.86 | 5.15 |
C 1 | 4.15 | 1.04 | 5.78 | 1.64 | ||
R 2 | 0.98 | 0.99 | 0.99 | 0.98 | ||
K dif2 (mg g−1 min1/2) | 1.69 | 2.55 | 2.50 | 1.87 | ||
C 2 | 40.70 | 33.12 | 62.57 | 33.17 | ||
R 2 | 0.96 | 0.96 | 0.92 | 0.97 |