Thermodynamic parameters for the adsorption of IC on MgOBi0, MgOBi1, MgOBi2, and MgOBi3.
Fed conc. (mg L−1) | ΔH° (kJ mol−1) | ΔS° (kJ mol−1) | ΔG° (kJ mol−1) 293 K | ΔG° (kJ mol−1) 308 K | ΔG° (kJ mol−1) 323 K |
---|---|---|---|---|---|
MgOBi0 | |||||
10 | 9.827 | 0.055 | −6.537 | −7.086 | −7.635 |
20 | 60.178 | 0.248 | −13.769 | −16.251 | −18.732 |
50 | 19.124 | 0.077 | −3.832 | −4.602 | −5.372 |
100 | 17.065 | 0.065 | −2.198 | −2.844 | −3.491 |
MgOBi1 | |||||
10 | 161.792 | 0.548 | −1.586 | −7.068 | −12.551 |
20 | 55.449 | 0.237 | −15.145 | −17.514 | −19.883 |
50 | 39.058 | 0.137 | −1.743 | −3.112 | −4.481 |
100 | 35.703 | 0.124 | −1.112 | −2.348 | −3.583 |
MgOBi2 | |||||
10 | 81.818 | 0.288 | −4.140 | −7.025 | −9.909 |
20 | 101.992 | 0.384 | −12.518 | −16.361 | −20.204 |
50 | 50.377 | 0.175 | −1.851 | −3.603 | −5.356 |
100 | 33.710 | 0.122 | −2.568 | −3.786 | −5.003 |
MgOBi3 | |||||
10 | 125.227 | 0.429 | −2.738 | −7.033 | −11.327 |
20 | 71.800 | 0.287 | −13.795 | −16.667 | −19.540 |
50 | 45.175 | 0.154 | −0.777 | −2.319 | −3.861 |
100 | 28.923 | 0.100 | −0.894 | −1.894 | −2.895 |