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. 2022 Sep 1;12(38):24998–25005. doi: 10.1039/d2ra04668g

Substrate tolerance of various alkynes over CuO/CNF nanocatalysta.

graphic file with name d2ra04668g-u2.jpg
Entry Alkyne Product Conv.b (%)
1 graphic file with name d2ra04668g-u3.jpg graphic file with name d2ra04668g-u4.jpg 96 (93)c
2 graphic file with name d2ra04668g-u5.jpg graphic file with name d2ra04668g-u6.jpg 93 (89)c
3 graphic file with name d2ra04668g-u7.jpg graphic file with name d2ra04668g-u8.jpg 85 (79)c
4 graphic file with name d2ra04668g-u9.jpg graphic file with name d2ra04668g-u10.jpg 88 (82)c
5 graphic file with name d2ra04668g-u11.jpg graphic file with name d2ra04668g-u12.jpg 91 (85)c
6 graphic file with name d2ra04668g-u13.jpg graphic file with name d2ra04668g-u14.jpg 86 (81)c
7 graphic file with name d2ra04668g-u15.jpg graphic file with name d2ra04668g-u16.jpg 85 (83)c
8 graphic file with name d2ra04668g-u17.jpg graphic file with name d2ra04668g-u18.jpg 91 (87)c
9 graphic file with name d2ra04668g-u19.jpg graphic file with name d2ra04668g-u20.jpg 89 (84)c
10 graphic file with name d2ra04668g-u21.jpg graphic file with name d2ra04668g-u22.jpg 74
11 graphic file with name d2ra04668g-u23.jpg graphic file with name d2ra04668g-u24.jpg 97
12 graphic file with name d2ra04668g-u25.jpg graphic file with name d2ra04668g-u26.jpg 86 (81)c
a

Experimental conditions: alkyne (1 mmol), B2Pin2 (1.2 mmol), CuO/CNF (2 mg), base (10 mol%), methanol (1 mL) under argon, 40 °C, 12 h.

b

Conversion determined by GC-MS.

c

Isolated yield.