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. 2022 Aug 23;7(35):31069–31080. doi: 10.1021/acsomega.2c03140

Table 2. Isotherm Parameters of Langmuir, Freundlich, Sips, and Dubinin–Radushkevich Models for the Sorption of As(III) and As(V) onto the AMOX-Type Sorbents, at 22 °C.

  AMOX1
AMOX2
AMOX3
isotherm parameters As(III) As(V) As(III) As(V) As(III) As(V)
Langmuir Model:
graphic file with name ao2c03140_m008.jpg
qm, mmol g−1 4.3108 3.934 4.5454 4.3926 4.68 4.6376
KL, L mmol–1 1.852 0.7782 2.3527 0.9878 3.6455 1.4076
R2 0.9286 0.8571 0.9387 0.8953 0.9761 0.9155
χ2 0.14 0.21 0.14 0.2 0.06 0.2
Freundlich Model:
graphic file with name ao2c03140_m009.jpg
KF, mmol1–1/n·L1/n·g–1 2.2598 1.54 2.522 1.882 2.867 2.2357
1/n 0.302 0.3843 0.2871 0.363 0.2612 0.331
R2 0.7309 0.6919 0.7384 0.7195 0.8023 0.7311
χ2 0.53 0.46 0.6 0.53 0.5 0.6
Sips Model:
graphic file with name ao2c03140_m010.jpg
qm, mmol g–1 3.803 3.1287 4.068 3.6491 4.3835 3.98
aS 7.01 2.581 10.856 2.996 9.13 5.575
1/n 1.997 2.846 2.011 2.464 1.484 2.302
R2 0.9952 0.9879 0.9972 0.9971 0.9895 0.9947
χ2 0.01 0.02 0.006 0.01 0.027 0.02
Dubinin–Radushkevich Model:
graphic file with name ao2c03140_m011.jpg
qDR, mol g–1 0.00739 0.00767 0.00766 0.00734 0.00809 0.00826
β, mol2 J–2 4.015 × 10–9 3.734 × 10–9 3.250 × 10–9 5.432 × 10–9 5.034 × 10–9 4.458 × 10–9
E, kJ mol–1 11.16 11.57 12.4 9.59 9.97 10.59
R2 0.7937 0.8021 0.8653 0.7952 0.8173 0.8287
χ2 0.0001 0.0001 0.0001 0.0001 0.0001 0.0001