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. 2022 Aug 25;27(17):5457. doi: 10.3390/molecules27175457

Table 2.

Catalytic performance of POMs-based photocatalysts for benzene hydroxylation.

Photocatalyst Reaction Conditions Con./% Sel./% Yield/% Ref.
IL-POMS
(25 μmol)
Xe lamp (λ > 420 nm), 1.28 mmol benzene, 10 mL CH3CN, 1 mL H2O, RT, 10 h. 21 99 20.9 [59]
NH2-MIL-88/
PMo10V2
(20 mg)
LED lamp (320–780 nm), 1 mL benzene, 3 mL acetic acid,
3 mL CH3CN, 1 mL H2O2, 60 °C, 3 h
12.5 99 12.4 [60]
Quinolinium and Polyoxovanadate-Based Supramolecular
(0.0125 mmol)
Xe lamp (λ > 420 nm), H2O:CH3CN = 3:17(v:v),
0.5 mmol benzene, 25 °C, 12 h
51 99 50.8 [61]