Table 4.
Catalytic performance of MOFs-based photocatalysts for benzene hydroxylation.
| Photocatalyst | Reaction Conditions | Con./% | Sel./% | Yield/% | Ref. |
|---|---|---|---|---|---|
| MIL-100(Fe) (10 mg) |
Xenon lamp (λ > 420 nm), 0.5 mmol benzene, 2 mL H2O, 2 mL CH3CN, 0.375 mmol H2O2, RT, 8 h | 20.1 | 98 | 19.5 | [82] |
| MIL-100(Fe) (25 mg) |
Xenon lamp (λ > 420 nm), 1 mmol benzene, 5 mL H2O, 3 mL CH3CN, 0.6 mmol H2O2, RT, 3–21 h | 34.4 | 98 | 33.8 | [83] |
| Cu (II) MOF (10 mg) |
LED lamp (λ > 420 nm), 1 mmol benzene, 10 mL H2O, 1.25 mmol H2O2, 60 °C, 10 h | 29 | 95 | 27.4 | [84] |
| UiO-66-NH2-SA-V (10 mg) |
Xenon lamp (λ > 420 nm), 1 mL benzene, 5 mL CH3CN, 1 mL acetic acid, H2O2, 60 °C, 4 h | 15.3 | 100 | 15.3 | [85] |
| NH2-MIL-88B(Fe)-SA-V (30 mg) |
Visible light, 1 mL benzene, 18 mL acetic acid, H2O2, 60 °C, 4 h | 22.5 | 98.6 | 22.2 | [86] |