C0 = concentrations of benzene and toluene in mg L−1 at the start |
Ce = concentrations of benzene and toluene in mg L−1 at equilibrium |
V = benzene and toluene volume at mL |
m = Fe3O4@ZIF-8 masses in mg |
KL = (L mg−1) is the Langmuir adsorption constant |
KF = Freundlich constant (L g−1) |
n = heterogeneity factor (If the value of n < 1, the adsorption is a chemical process; if n > 1, then it is a physical process). |
qe = adsorption capacity at equilibrium |
qm = maximum adsorption capacity |
RL = dimensionless separation factor |
The values of RL show whether the biosorption process is irreversible (RL = 0), linear (RL = 1), favorable (0 < RL < 1) or undesirable (RL > 1) |
ΔG° = Gibbs free energy (kJ mol−1) |
ΔS° = entropy (kJ mol−1 K−1) |
ΔH° = enthalpy (kJ mol−1) |
K1 = equilibrium rate constant for pseudo-first order kinetics (PFO) (1.min−1) |
K2 = equilibrium rate constant for pseudo-second order kinetics (PSO) (g mg−1 minmg) |
Kb =Intra-Particle Diffusion (IPD) rate constant (mg g−1 min−1/2) |
C= thickness of the boundary layer |
D-R isotherm constant (mol2 kJ−2) |
Polanyi potential |
E = The adsorption energy (kJ.mol−1) |
KT = constant of equilibrium binding (L.mg−1) |
B = Temkin constant associated with the heat of adsorption (J/mol) |
D-R = Dubinin-Radushkevich |
XRD = X-ray Powder Diffraction |
FTIR= Fourier Transform Infrared Spectrometer |
SEM = Scanning electron microscope |
TEM = Transmission Electron Microscope |
VSM = Vibrating Sample Magnetometer |
BET = Brunauer–Emmett–Teller |
MOF = Metal-organic framework |