| Sn1—Cl1 | 2.4162 (5) | C1—C2 | 1.417 (3) |
| Sn1—Cl1i | 2.4162 (5) | C1—N2 | 1.315 (3) |
| Sn1—Cl2 | 2.4389 (5) | C2—C3 | 1.356 (3) |
| Sn1—Cl2i | 2.4389 (5) | C2—Cl4 | 1.713 (2) |
| Sn1—Cl3 | 2.4253 (5) | C3—H3 | 0.9300 |
| Sn1—Cl3i | 2.4253 (5) | C3—C4 | 1.393 (3) |
| O1W—H1WA | 0.8499 | C4—C5 | 1.348 (3) |
| O1W—H1WB | 0.8496 | C4—Cl5 | 1.726 (2) |
| N1—H1 | 0.8600 | C5—H5 | 0.9300 |
| N1—C1 | 1.345 (3) | N2—H2A | 0.8600 |
| N1—C5 | 1.350 (3) | N2—H2B | 0.8600 |
| Cl1—Sn1—Cl1i | 180.0 | N1—C1—C2 | 116.00 (18) |
| Cl1—Sn1—Cl2 | 90.722 (19) | N2—C1—N1 | 119.49 (18) |
| Cl1i—Sn1—Cl2 | 89.278 (19) | N2—C1—C2 | 124.50 (19) |
| Cl1—Sn1—Cl2i | 89.277 (19) | C1—C2—Cl4 | 117.52 (16) |
| Cl1i—Sn1—Cl2i | 90.723 (19) | C3—C2—C1 | 120.82 (18) |
| Cl1—Sn1—Cl3 | 89.906 (19) | C3—C2—Cl4 | 121.66 (15) |
| Cl1—Sn1—Cl3i | 90.093 (19) | C2—C3—H3 | 120.1 |
| Cl1i—Sn1—Cl3i | 89.907 (19) | C2—C3—C4 | 119.71 (18) |
| Cl1i—Sn1—Cl3 | 90.093 (19) | C4—C3—H3 | 120.1 |
| Cl2i—Sn1—Cl2 | 180.0 | C3—C4—Cl5 | 120.22 (16) |
| Cl3i—Sn1—Cl2 | 89.81 (2) | C5—C4—C3 | 119.70 (19) |
| Cl3i—Sn1—Cl2i | 90.19 (2) | C5—C4—Cl5 | 120.08 (18) |
| Cl3—Sn1—Cl2 | 90.19 (2) | N1—C5—H5 | 120.3 |
| Cl3—Sn1—Cl2i | 89.81 (2) | C4—C5—N1 | 119.4 (2) |
| Cl3—Sn1—Cl3i | 180.0 | C4—C5—H5 | 120.3 |
| H1WA—O1W—H1WB | 109.5 | C1—N2—H2A | 120.0 |
| C1—N1—H1 | 117.8 | C1—N2—H2B | 120.0 |
| C1—N1—C5 | 124.32 (17) | H2A—N2—H2B | 120.0 |
| C5—N1—H1 | 117.8 | ||
| N1—C1—C2—C3 | 0.4 (3) | C5—N1—C1—C2 | −0.6 (3) |
| N1—C1—C2—Cl4 | −178.93 (15) | C5—N1—C1—N2 | 178.8 (2) |
| C1—N1—C5—C4 | 0.3 (3) | N2—C1—C2—C3 | −179.0 (2) |
| C1—C2—C3—C4 | 0.0 (3) | N2—C1—C2—Cl4 | 1.7 (3) |
| C2—C3—C4—C5 | −0.3 (3) | Cl4—C2—C3—C4 | 179.31 (16) |
| C2—C3—C4—Cl5 | −179.42 (16) | Cl5—C4—C5—N1 | 179.25 (16) |
| C3—C4—C5—N1 | 0.1 (3) |