Table 2.

Nonequivalent Chemical Shifts (ΔΔδ, ppm) of Other Split Protons of (±)-G1–14 in the Presence of TAMCSAs 1a–1c in CDCl₃ (400 or 600 MHz) at 25 °C^a

guest/TAMCSA	proton	ΔΔδ	guest/TAMCSA	proton	ΔΔδ
(±)-G1/1a	PhCH	0.030	(±)-G9/1bb	4-PhCH2CH	0.024
(±)-G1/1bb	PhCH	0.041	(±)-G9/1ce	PhCH3	0.007
(±)-G1/1c	PhCH	0.029		4-PhCH2CH	0.052
(±)-G2/1a	PhCH2	0.091	(±)-G10/1ac	CH 2	0.070
		0.049		α-H(trp unit)	0.036
	PhCH2CH	0.042		ArH	0.012
(±)-G2/1bb	PhCH2	0.061		ArH	0.119
		0.040		C═CHNH	0.031
	PhCH2CH	0.031	(±)-G10/1bf	CH 2	0.051
(±)-G2/1cc	PhCH2	0.111		α-H(trp unit)	0.027
		0.054		ArH	0.067
	PhCH2CH	0.051		ArH	0.013
(±)-G3/1ac,i	CH 3	0.049	(±)-G10/1cb	CH 2	0.045
(±)-G3/1bb	CH 3	0.020		α-H(trp unit)	0.029
(±)-G3/1cd,i	CH 3	0.029		ArH	0.078
(±)-G4/1a	(CH3)2CHCH	0.014		C═CHNH	0.030
		0.042	(±)-G11/1ac	PhCH2	0.153
	(CH3)2CHCH	0.031			0.100
(±)-G4/1b	(CH3)2CHCH	0.007		PhCH2CH	0.086
		0.022		ArH	0.061
	(CH3)2CHCH	0.024		ArH	0.014
(±)-G4/1cb	(CH3)2CHCH	0.013	(±)-G11/1bb	PhCH2	0.095
		0.044			0.068
	(CH3)2CHCH	0.037		PhCH2CH	0.077
(±)-G5/1ae	CH 3	0.018		ArH	0.058
		0.007		ArH	0.012
	(CH3)2CHCH2CH	0.039	(±)-G11/1cc	PhCH2	0.154
(±)-G5/1bc	CH 3	0.022			0.087
		0.008		PhCH2CH	0.080
	(CH3)2CHCH2CH	0.059		ArH	0.061
(±)-G5/1c	CH 3	0.020		ArH	0.013
		0.008	(±)-G12/1ah	CH 3	0.034
	(CH3)2CHCH2CH	0.045		ArH	0.016
(±)-G6/1ab	SCH3	0.030	(±)-G12/1bd	CH 3	0.017
(±)-G6/1bb	SCH3	0.021		ArH	0.032
(±)-G6/1cb	SCH3	0.025	(±)-G12/1cb	CH 3	0.032
(±)-G7/1ac	PhCH3	0.038		ArH	0.019
(±)-G7/1bc	PhCH3	0.023	(±)-G13/1ab	ArH	0.026
(±)-G7/1cc	PhCH3	0.033		ArH	0.012
(±)-G8/1ab	CH 3	0.040	(±)-G13/1bb	ArH	0.014
	PhCH3	0.037		ArH	0.040
	CH3(OH)CHCH	0.027	(±)-G13/1cc	ArH	0.022
(±)-G8/1bf	CH 3	0.050		ArH	0.029
	PhCH3	0.025	(±)-G14/1ab,j	CH 3	0.024
	CH3(OH)CHCH	0.024		CH3(OH)CHCH	0.028
(±)-G8/1cb	CH 3	0.038	(±)-G14/1bb,j	CH 3	0.009
	PhCH3	0.035		CH3(OH)CHCH	0.022
	CH3(OH)CHCH	0.027	(±)-G14/1cj	CH 3	0.018
(±)-G9/1ag	PhCH3	0.005		CH3(OH)CHCH	0.021
	4-PhCH2CH	0.030

^a5.0 mM.

^b7.5 mM.

^c10.0 mM.

^d6.0 mM.

^e4.0 mM.

^f12.5 mM.

^g2.0 mM.

^h3.0 mM.

ⁱ600 MHz.

^jCDCl₃ (10% CD₃COCD₃).