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. 2018 Dec 28;1(3):1181–1185. doi: 10.1039/c8na00192h

Scope of the AuCNT-promoted oxidative esterification of alcohols 1a.

graphic file with name c8na00192h-u2.jpg
Entry Alcohol 1 Ester 2 Time (d) Yieldb (%)
1 graphic file with name c8na00192h-u3.jpg 2a 2 85
2 graphic file with name c8na00192h-u4.jpg 2b 2 92
3 graphic file with name c8na00192h-u5.jpg 2c 2 87
4 graphic file with name c8na00192h-u6.jpg 2d 3 83
5 graphic file with name c8na00192h-u7.jpg 2e 4 85
6 graphic file with name c8na00192h-u8.jpg 2f 4 89
7 graphic file with name c8na00192h-u9.jpg 2g 4 76
8 graphic file with name c8na00192h-u10.jpg 2h 4 70
9 graphic file with name c8na00192h-u11.jpg 4 nrc
10 graphic file with name c8na00192h-u12.jpg 4 nrc
11 graphic file with name c8na00192h-u13.jpg 4 nrc
12 graphic file with name c8na00192h-u14.jpg 4 nrc
13 graphic file with name c8na00192h-u15.jpg 4 nrc
a

Reaction conditions: 1 (0.1 mmol), AuCNT (0.54 mol%), MeOH (1 mL), NaOH (0.15 mmol), air, room temp.

b

Yield of isolated product.

c

No reaction.