Table 3.

Multi-compounds contents in Gelsemium elegans samples.

No.	Analytes	S1	S2	S3	S4	S5	S6	S7	S8	S9
1	7-Deoxygelsemide or 9-Deoxygelsemide	–	–	0.004	–	–	0.001	–	–	0.001
2	11,14-Dihydroxygelsenicine	0.043	0.041	0.114	0.012	0.058	0.193	0.009	0.148	0.472
3	14,15-Dihydroxygelsenicine	0.032	0.032	0.087	0.009	0.045	0.148	0.009	0.114	0.365
4	Unknown (375)	0.037	0.007	0.005	0.032	0.015	0.015	0.043	0.015	0.009
5	Gelsemine	3.036	4.145	4.679	2.208	3.014	3.565	3.956	4.678	3.19
6	11-Hydroxygelsenicine	0.048	0.032	0.08	0.008	0.039	0.009	0.002	0.003	0.006
7	Gelsemicine	–	–	–	0.001	0.001	0.002	0.003	0.004	0.004
8	GSIR-1	0.001	0.001	0.003	–	–	0.001	–	–	0.001
9	14-Hydroxygelsemicine or other hydroxylation of gelsemicine	0.424	0.145	0.129	0.273	0.187	0.13	0.417	0.136	0.088
10	14-Hydroxygelsedine	0.048	0.005	0.007	0.066	0.005	0.004	0.132	0.008	0.005
11	14-Hydroxygelsenicine	0.383	0.171	0.576	0.704	0.407	0.552	0.951	1.198	0.925
12	Koumine	1.376	0.644	0.693	1.089	0.562	0.51	1.772	0.333	0.197
13	14-Dehydroxygelsefuranidine or other dehydroxylgelsefuranidine (2)	0.076	0.037	0.106	0.064	0.041	0.143	0.117	0.03	0.097
14	11-Methoxy-14-hydroxygelsenicine	0.064	0.02	0.099	0.133	0.069	0.091	0.224	0.182	0.169
15	Unknown (295)	0.077	0.039	0.023	0.071	0.027	0.016	0.152	0.025	0.008
16	Hydroxyl of gelsedine	0.001	–	–	–	–	–	0.003	–	–
17	Gelsemoxonine	0.158	0.04	0.455	0.167	0.207	1.994	0.617	1.066	3.185
18	One of other five hit compounds	0.08	0.028	0.065	0.069	0.022	0.071	0.184	0.017	0.039
19	14-Dehydroxygelsefuranidine or other dehydroxylgelsefuranidine (1)	0.059	0.013	0.034	0.06	0.01	0.046	0.111	0.019	0.03
20	koumidine	0.022	0.04	0.02	0.028	0.028	0.022	0.107	0.028	0.012
21	14-Acetoxygelsedilam or other Acetoxyl of gelsedilam (1)	0.01	0.01	0.008	0.001	0.005	0.003	0.004	0.003	0.003
22	11-Hydroxyhumantenine	0.987	1.069	0.963	0.186	0.541	0.185	0.077	0.097	0.1
23	Gelsevirine	0.257	0.108	0.062	0.389	0.08	0.02	0.631	0.03	0.007
24	Gelsenicine	0.944	0.228	0.823	1.085	0.805	0.55	1.508	0.901	0.488
25	12β-Hydroxy-pregn-4,16-diene-3,20-dione	0.002	–	0.001	0.002	0.001	0.001	0.002	0.001	0.001
26	Koumicine	0.326	0.237	0.349	0.219	0.217	0.446	0.441	0.199	0.327
27	Gelsedine or Nb-Methylgelsedilam	0.007	0.001	0.002	0.006	0.002	0.001	0.01	0.001	0.001
28	Gelseoxazolidinine	0.015	0.005	0.01	0.002	–	0.003	0.002	–	0.001
29	16-epi-Voacarpine or gelsevirine N-oxide	0.853	0.514	0.812	0.57	0.645	1.13	0.934	0.817	1.033
30	Humantenoxenine	0.006	0.008	0.02	0.003	0.004	0.013	0.009	0.009	0.011
31	Iso-Gelsedine or Nb-Methylgelsedilam	0.012	0.002	0.002	0.042	0.001	0	0.042	0.001	–
32	1-O-Caffeoylquinic acid or 4-O-Caffeoylquinic acid	0.176	0.044	0.072	0.165	0.059	0.071	0.268	0.064	0.045
33	Gelseziridine	0.001	–	–	0.003	–	0.001	0.004	–	–
34	Na-Desmethoxyhumantenine	0.028	0.005	0.012	0.028	0.01	0.014	0.046	0.012	0.009
35	14-Acetoxygelsedilam or other Acetoxyl of gelsedilam (2)	0.039	0.008	0.019	0.068	0.019	0.02	0.069	0.019	0.019
36	14-Acetoxygelsedilam or other Acetoxyl of gelsedilam (3)	0.028	0.009	0.023	0.087	0.017	0.019	0.09	0.018	0.018
37	19R-Hydroxydihydrogelsevirine or 19S-Hydroxydihydrogelsevirine	3.436	1.261	1.335	9.918	2.4	2.677	10.567	1.584	2.629
38	11-Methoxyhumantenine	0.105	0.08	0.04	0.081	0.034	0.034	0.272	0.016	0.011
39	iso-12β-Hydroxy-5α-pregn-16-ene-3,20-dione	0.004	0.001	0.004	0.002	–	0.006	0.008	–	0.005
40	Gelse-norursane E	0.012	0.001	0.002	0.006	0.001	0.007	0.036	0.001	0.003

Note: -, nondetected.