Optical properties of selected compounds 4 and 5 in CH2Cl2.
| 4/5 | λ abs (nm) (ε (104 M−1 cm−1)) | λ em a (nm) | Φ F b (%) | Δνc (cm−1) |
|---|---|---|---|---|
| 4abd | 415 (1.73) | 565 | 90 | 6397 |
| 4af | 334 (3.05), 422 (1.90)e | 572 | 48 | 6214 |
| 4ag | 294 (1.87), 348 (1.04), 370 (1.19)e | 512 | 83 | 7496 |
| 4aq | 380 (1.73) | 471 | 20 | 5085 |
| 4as | 388 (2.03) | 481, 505 | 23 | 4983 |
| 4at | 380 (2.55) | 479, 499 | 39 | 5439 |
| 4au | 438 (3.08), 465 (3.78), 490 (2.89)e | 548 | 25 | 2160 |
| 4av | 344 (2.0), 385 (1.77)e | 540 | 32 | 7455 |
| 5aa | 297 (1.97), 364 (0.81), 382 (0.56)e | 425 | 56 | 2649 |
| 5ab | 278 (3.19), 304 (2.78), 438 (1.81)e | 533 | 87 | 4069 |
| 5ac | 306 (0.19), 370 (0.11), 395 (0.10)e | 446 | 95 | 2894 |
Excited at λabs.
Absolute fluorescence quantum yields.
Stokes shifts.
The optical data of 4ab in CH2Cl2 was reported by Yamaguchi et al. in ref. 3a.
Absorption maxima at the longest wavelength.