Summary of XPS functional group details of the various surface treated FLCS. All data reported is an average of at least N = 3 samples.
Peak positions, eV | FLCS | FLCS-corona | FLCS-1 h PDA | FLCS-12 h PDA | FLCS-24 h PDA | |
---|---|---|---|---|---|---|
C 1s | 284.8 (C–C, C–H) | 45 | 36 | 54 | 51 | 43 |
285.5 (C–O) | 23 | 16 | — | — | — | |
286.1 (C–OH, C–N) | 20 | 29 | 36 | 36 | 42 | |
288.0 (C O) | — | — | 1 | 8 | 9 | |
289.1 (O C–O) | 13 | 19 | 8 | 4 | 4 | |
291.5 (π → π* shakeup) | — | — | — | 2 | 2 | |
N 1s | 398.2 (R N–R) | — | — | 13 | 11 | 11 |
400.0 (R–NH–R) | 100 | 66 | 68 | 60 | 67 | |
401.0 (R–NH2) | — | 28 | 16 | 29 | 22 | |
405.0 (R–NO2) | — | 6 | 3 | — | — |