Table 1.
1H and 13C chemical shifts of TFP-F1.
| Residues and Linkage | H-1/C-1 | H-2/C-2 | H-3/C-3 | H-4/C-4 | H-5/C-5 | H-6/C-6 |
|---|---|---|---|---|---|---|
| A. →2)-β-D-Xylp-(1→ | 4.37/101.7 | 3.50/74.1 | 3.59/77.7 | 3.55/71.8 | 3.94; 3.21/65.1 | -/- |
| B.-β-D-GlcAp-(1→ | 4.44/102.2 | 3.33/72.6 | 3.41/75.3 | 3.53/71.8 | 3.65/77.0 | -/175.7 |
| C. →2, 3)-α-D-Manp-(1→ | 5.06/101.3 | 4.15/78.1 | 3.94/76.1 | 3.70/66.3 | 3.75/73.5 | 3.86; 3.46/61.6 |
| D. →3)-α-D-Manp-(1→ | 5.10/102.3 | 4.17/69.9 | 3.94/79.1 | 3.71/66.3 | 3.78/73.6 | 3.82; 3.70/61.4 |
| E. →2, 3)-α-D-Manp-(1→ | 5.13/100.7 | 4.23/77.9 | 4.03/77.2 | 3.77/66.4 | 3.78/73.6 | 3.78; 3.78/60.6 |
| F. -α-L-Fucp-(1→ | 5.47/97.4 | 3.72/68.2 | 3.78/69.4 | 3.71/72.2 | 4.29/66.6 | 1.15/15.7 |