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. 2022 Sep 15;14(18):3860. doi: 10.3390/polym14183860

Table 1.

Comparison of particle size, particle shape, and electrical conductivity of P3HT with previous works.

Synthesis Method Surfactant Type Particle Size (nm) Particle Shape Electrical
Conductivity
(S cm−1)
Sample Code Ref.
Chemical oxidative polymerization - 157 ± 33 Irregular 3.12 ± 0.44 P3HT at 6 h -
- 141 ± 21 Irregular 8.09 ± 0.12 P3HT at 12 h -
- 280 ± 62 Agglomerated 3.04 ± 0.43 P3HT at 18 h -
- 311 ± 69 Agglomerated 2.33 ± 0.20 P3HT at 24 h -
- 650 ± 197 Irregular 0.24 ± 0.05 3HT:FeCl3 = 1:2.5 -
- 141 ± 21 Irregular 8.09 ± 0.12 3HT:FeCl3 = 1:3 -
- 191 ± 48 Agglomerated 1.23 ± 0.36 3HT:FeCl3 = 1:3.5 -
- 347 ± 139 Agglomerated 0.49 ± 0.12 3HT:FeCl3 = 1:4 -
Emulsion polymerization DBSA 244 ± 58 Sphere cluster and fiber 5.82 ± 1.38 P3HT_DBSA 2 CMC -
542 ± 139 Spherical 7.05 ± 0.74 P3HT_DBSA 4 CMC -
1526 ± 227 Grape shape 16.21 ± 1.55 P3HT_DBSA 6 CMC -
672 ± 192 Sphere cluster 10.41 ± 2.27 P3HT_DBSA 8 CMC -
516 ± 131 Sphere cluster and fiber 3.17 ± 0.13 P3HT_DBSA 10 CMC -
PTSA 356 ± 65 Irregular 1.07 ± 0.05 P3HT_PTSA 2 CMC -
316 ±82 Irregular 3.13 ± 0.30 P3HT_PTSA 4 CMC -
254 ± 58 Coral reef shape 6.33 ± 0.27 P3HT_PTSA 6 CMC -
364 ± 118 Fused spheres and fiber 0.82 ± 0.04 P3HT_PTSA 8 CMC -
414 ± 70 Fused spheres and fiber 0.04 ± 0.01 P3HT_PTSA 10 CMC -
SDS 247 ± 38 Spherical 0.41 ± 0.03 P3HT_SDS 2 CMC -
234 ± 48 Spherical 2.80 ± 0.18 P3HT_SDS 4 CMC -
300 ± 49 Spherical 0.76 ± 0.08 P3HT_SDS 6 CMC -
498 ± 98 Sphere cluster 0.58 ± 0.12 P3HT_SDS 8 CMC -
817 ± 54 Sphere cluster 0.35 ± 0.02 P3HT_SDS 10 CMC -
AOT 348 ± 92 Spherical 0.06 ± 0.01 P3HT_AOT 2 CMC -
335 ± 97 Spherical and fiber 0.11 ± 0.03 P3HT_AOT 4 CMC -
269 ± 98 Spherical and fiber 0.65 ± 0.05 P3HT_AOT 6 CMC -
278 ± 73 Spherical and fiber 0.57 ± 0.02 P3HT_AOT 8 CMC -
291 ± 53 Spherical and fiber 0.37 ± 0.03 P3HT_AOT 10 CMC -
De-doping with NH4OH - 1545 ± 861 Spherical 2.01 × 10−5 deP3HT_DBSA -
Doped with HClO4 - 1223 ± 718 Spherical 74.81 ± 5.22 dP3HT_DBSA (1:1) -
- 1232 ± 463 Spherical 120.56 ± 8.10 dP3HT_DBSA (5:1) -
- 1110 ± 494 Spherical 172.74 ± 7.02 dP3HT_DBSA (10:1) -
- 1389 ± 873 Spherical 159.68 ± 6.11 dP3HT_DBSA (25:1) -
- 1170 ± 654 Spherical 138.24 ± 9.25 dP3HT_DBSA (50:1) -
- 1530 ± 827 Spherical 110.70 ± 8.01 dP3HT_DBSA (75:1) -
In situ polymerization - - Agglomerated 2.30 × 105 P3HT [48]
- - Tubular 0.71 P3HT_MWNT [48]
Chemical oxidative polymerization - - Agglomerated 1.20 P3HT_GNs [34]
- - - 3.00 P3HT [21]
- - - 1.82 ± 0.22 P3HT doped with F4TCNQ [22]