Table 10.

Results of CO epoxidation under organic solvent-free conditions with vanadium complexes from Figure 20.

General Formula	R or X	Conv. (%)	Sel. (%)	TOF20min	TON
[V2O3L2]	R = H	61	35	2339	1251
[V2O3(LH)2]Cl2	R = H	87	32	2409	1804
[V2O3L2] × 2 MeOH	R = Ph	67	32	1587	1386
[V2O3(LH)2]Cl2 × 2 MeOH	R = Ph	74	36	1930	1551
[VO2(LH)] × MeOH × H2O	X = C-H	23	10	940	532
[VO2(LH)] × MeOH × H2O	X = C-OH	33	10	1571	700
[VO2(LH)]	X = N	31	13	1179	633