Table 3. Selected Bond Lengths and Bond Angles for Complexes I–III.
| atoms | bond lengths | atoms | bond lengths | atoms | bond angles | atoms | bond angles |
|---|---|---|---|---|---|---|---|
| Complex I | |||||||
| U(1)–O(2) | 1.756(7) | O(3)–C(7) | 1.280(14) | O(2)–U(1)–O(1) | 178.8(4) | O(3)–U(1)–O(4) | 71.3(3) |
| U(1)–O(1) | 1.762(7) | O(4)–C(11) | 1.266(14) | O(2)–U(1)–O(5) | 91.8(4) | O(7)–U(1)–O(4) | 70.4(3) |
| U(1)–O(5) | 2.337(8) | O(5)–C(24) | 1.252(14) | O(1)–U(1)–O(5) | 89.3(3) | O(2)–U(1)–O(6) | 90.0(3) |
| U(1)–O(3) | 2.366(8) | O(6)–C(28) | 1.262(13) | O(2)–U(1)–O(3) | 88.0(3) | O(1)–U(1)–O(6) | 90.1(3) |
| U(1)–O(7) | 2.393(7) | N(1)–C(7) | 1.346(14) | O(1)–U(1)–O(3) | 90.9(3) | O(5)–U(1)–O(6) | 71.2(3) |
| U(1)–O(4) | 2.411(8) | N(1)–C(1) | 1.394(14) | O(5)–U(1)–O(3) | 146.4(3) | O(3)–U(1)–O(6) | 75.1(3) |
| U(1)–O(6) | 2.416(7) | N(1)–N(2) | 1.418(13) | O(2)–U(1)–O(7) | 88.0(3) | O(7)–U(1)–O(6) | 143.2(3) |
| Cl(1)–C(15) | 1.734(11) | N(2)–C(9) | 1.322(14) | O(1)–U(1)–O(7) | 92.6(3) | O(4)–U(1)–O(6) | 146.4(3) |
| Cl(2)–C(32) | 1.756(11) | N(3)–C(24) | 1.357(15) | O(5)–U(1)–O(7) | 72.1(3) | C(7)–O(3)–U(1) | 132.4(6) |
| O(3)–C(7) | 1.280(14) | N(3)–N(4) | 1.405(13) | O(3)–U(1)–O(7) | 141.4(3) | C(11)–O(4)–U(1) | 136.5(7) |
| O(4)–C(11) | 1.266(14) | N(3)–C(18) | 1.450(14) | O(2)–U(1)–O(4) | 90.7(3) | C(24)–O(5)–U(1) | 126.1(8) |
| O(5)–C(24) | 1.252(14) | N(4)–C(26) | 1.294(15) | O(1)–U(1)–O(4) | 88.6(3) | C(28)–O(6)–U(1) | 135.9(7) |
| O(6)–C(28) | 1.262(13) | S(1)–O(7) | 1.533(8) | O(5)–U(1)–O(4) | 142.3(2) | O(6)–C(28)–C(25) | 121.8(10) |
| Complex II | |||||||
| U(1)–O(1) | 1.7722(15) | O(5)–C(24) | 1.275(2) | O(1)–U(1)–O(2) | 179.11(8) | O(6)–U(1)–O(5) | 71.82(5) |
| U(1)–O(2) | 1.7746(15) | O(6)–C(28) | 1.275(2) | O(1)–U(1)–O(4) | 89.82(7) | O(3)–U(1)–O(5) | 145.99(5) |
| U(1)–O(4) | 2.3312(14) | N(1)–C(9) | 1.315(2) | O(2)–U(1)–O(4) | 90.25(6) | O(1)–U(1)–O(7) | 88.95(7) |
| U(1)–O(6) | 2.3477(14) | N(1)–N(2) | 1.397(2) | O(1)–U(1)–O(6) | 89.05(6) | O(2)–U(1)–O(7) | 90.24(7) |
| U(1)–O(3) | 2.3666(14) | N(2)–C(11) | 1.360(2) | O(2)–U(1)–O(6) | 91.38(6) | O(4)–U(1)–O(7) | 72.54(5) |
| U(1)–O(5) | 2.3833(13) | N(2)–C(12) | 1.414(2) | O(4)–U(1)–O(6) | 145.51(5) | O(6)–U(1)–O(7) | 141.88(5) |
| U(1)–O(7) | 2.4300(15) | N(3)–C(28) | 1.357(2) | O(1)–U(1)–O(3) | 90.84(7) | O(3)–U(1)–O(7) | 143.89(5) |
| Cl(1)–C(4) | 1.7384(19) | N(3)–N(4) | 1.397(2) | O(2)–U(1)–O(3) | 90.02(7) | O(5)–U(1)–O(7) | 70.06(5) |
| Cl(2)–C(14) | 1.726(2) | N(3)–C(29) | 1.415(2) | O(4)–U(1)–O(3) | 71.35(5) | C(7)–O(3)–U(1) | 140.06(13) |
| Cl(3)–C(21) | 1.7309(18) | N(4)–C(26) | 1.316(2) | O(6)–U(1)–O(3) | 74.20(5) | C(11)–O(4)–U(1) | 128.03(12) |
| Cl(4)–C(31) | 1.736(2) | O(7)–C(35) | 1.243(2) | O(1)–U(1)–O(5) | 87.23(6) | C(24)–O(5)–U(1) | 136.44(12) |
| O(3)–C(7) | 1.272(2) | O(8)–C(38) | 1.233(3) | O(2)–U(1)–O(5) | 92.17(6) | C(28)–O(6)–U(1) | 132.14(12) |
| O(4)–C(11) | 1.277(2) | C(38)–N(6) | 1.306(3) | O(4)–U(1)–O(5) | 142.53(5) | O(6)–C(28)–C(25) | 130.59(17) |
| Complex III | |||||||
| U(1)–O(2) | 1.759(4) | N(1)–C(11) | 1.351(7) | O(2)–U(1)–O(1) | 178.62(18) | O(5)–U(1)–O(4) | 71.93(13) |
| U(1)–O(1) | 1.763(4) | N(1)–N(2) | 1.396(6) | O(2)–U(1)–O(3) | 92.16(18) | O(6)–U(1)–O(4) | 143.42(14) |
| U(1)–O(3) | 2.347(4) | N(1)–C(12) | 1.416(7) | O(1)–U(1)–O(3) | 89.15(17) | O(2)–U(1)–O(7) | 90.76(18) |
| U(1)–O(5) | 2.348(4) | N(2)–C(9) | 1.306(7) | O(2)–U(1)–O(5) | 89.85(17) | O(1)–U(1)–O(7) | 90.05(16) |
| U(1)–O(6) | 2.375(4) | N(3)–C(29) | 1.343(7) | O(1)–U(1)–O(5) | 88.85(16) | O(3)–U(1)–O(7) | 71.41(13) |
| U(1)–O(4) | 2.385(4) | N(3)–N(4) | 1.405(7) | O(3)–U(1)–O(5) | 143.66(13) | O(5)–U(1)–O(7) | 144.86(13) |
| U(1)–O(7) | 2.385(4) | N(3)–C(30) | 1.419(7) | O(2)–U(1)–O(6) | 89.00(17) | O(6)–U(1)–O(7) | 73.34(13) |
| Cl(1)–C(4) | 1.733(6) | N(4)–C(27) | 1.305(7) | O(1)–U(1)–O(6) | 90.17(17) | O(4)–U(1)–O(7) | 143.21(14) |
| Cl(2)–C(22) | 1.732(6) | S(1S)–O(1S) | 1.527(5) | O(3)–U(1)–O(6) | 144.74(13) | O(3)–C(11)–N(1) | 124.0(5) |
| O(3)–C(11) | 1.276(7) | S(1T)–O(1T) | 1.527(5) | O(5)–U(1)–O(6) | 71.55(13) | O(3)–C(11)–C(8) | 129.3(5) |
| O(4)–C(7) | 1.264(7) | S(1T)–C(1T) | 1.746(7) | O(2)–U(1)–O(4) | 88.92(19) | O(5)–C(29)–N(3) | 123.2(5) |
| O(5)–C(29) | 1.272(7) | S(1)–C(38) | 1.767(6) | O(1)–U(1)–O(4) | 91.10(18) | O(5)–C(29)–C(26) | 130.2(5) |
| O(6)–C(25) | 1.281(7) | S(1S)–C(2S) | 1.766(6) | O(3)–U(1)–O(4) | 71.83(13) | O(7)–S(1)–C(37) | 106.6(3) |