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. 2022 Sep 13;144(38):17416–17422. doi: 10.1021/jacs.2c04711

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Ir-MnO_x catalysts for cyclooctene epoxidation. (A) Faradaic efficiency for cyclooctene epoxidation vs potentials. (B) Comparison of average epoxidation current between Ir_single-MnO_x, Ir_cluster-MnO_x, and MnO_x. (C) Cyclooctene concentration (at 5 M H₂O) and (D) water concentration (at 100 mM cyclooctene) dependences of average epoxide partial current at 1.4 V vs Fc/Fc⁺. Acetonitrile (ACN) was used as the solvent.