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. 2022 Sep 7;122(18):14911–14939. doi: 10.1021/acs.chemrev.2c00259

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© 2022 The Authors. Published by American Chemical Society

Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).

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Reaction scheme for (PtCO)₂ species on Fe₃O₄(001). Reaction occurs via a metastable configuration of the (PtCO)₂ and Fe₃O₄(001) support, which allows extraction of lattice oxygen at minimum energetic cost. In the schematics, the Fe_oct and Fe_tet of the Fe₃O₄(001) support are dark blue and cyan, respectively. O atoms are red, Pt are white, and C and O in CO are black and red, respectively. Reproduced from ref (119). Copyright 2022 American Association for the Advancement of Science under CC-BY license (https://creativecommons.org/licenses/by/4.0/).