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Relevant structural and spectroscopic parameters.
| Sample | Nε-Nε (Å) | Cu-Nε (Å) | λmax (nm) (ε / M−1cm−1) | Kd (fM) Cu(I)/Cu(II) | gx, gy | gz | Ax, Ay (MHz) | Az (MHz) |
|---|---|---|---|---|---|---|---|---|
| [3SCC-Cu(I9H)3]2+ | 3.41 | 2.03 | 590 (78) | 12 / 184 | 2.05 | 2.25 | 116 | 566 |
| [3SCC-Cu(I9H)3]2+ + H2O2 | -- | -- | 330 (6400) 387 (1400) 570 (75) |
-- | 2.06 | 2.27 | 97 | 530 |
| [3SCC-Cu(I9H)3]+ + H2O2 | -- | -- | 350 (11530) 440 (460) |
-- | 2.06 | 2.28 | 100 | 497 |
