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. Author manuscript; available in PMC: 2022 Sep 30.
Published in final edited form as: ACS Catal. 2021 Aug 3;11(16):10267–10278. doi: 10.1021/acscatal.1c02132

Table 2.

Redox and catalytic properties of the ArCuP.

pH Epc/mV Epa/mV E1/2/mV ▲Ep/mV ▲E1/2c/mV ▲El/2a/mV Ic/μA Ia/μA kcat /s−1
5.5 279 (±8) 298 (±8) 289 19 126 94 −6.9 (±0.2) 6.1 (±0.1) 0.45 (±0.01)
6.5 239 (±6) 273 (±5) 256 34 92 132 −7.1 (±0.1) 6.2 (±0.1) 0.54 (±0.02)
7.5 210 (±4) 248 (±3) 229 38 98 144 −6.7 (±0.1) 6.2 (±0.1) 0.70 (±0.02)
8.5 160 (±7) 218 (±5) 189 58 110 130 −6.8 (±0.1) 6.3 (±0.1) 0.65 (±0.02)
9.5 149 (±10) 203 (±8) 176 54 100 140 −6.7 (±0.1) 6.5 (±0.1) 0.62 (±0.02)