Table 1.
Summary of absorption and PL peaks, Stokes shifts, PL and photoisomerization quantum yields (QYs)
Compound | Solvent | Abs. peak (nm) | PL peak (nm) | Stokes shift (eV) | PLQY (%) | Photo-isomerization QY (%) |
---|---|---|---|---|---|---|
Motor | Toluene | 389 | – | – | a | 18b |
Acetone | 386 | – | – | 12b | ||
BODIPY | Toluene | 500 | 510 | 0.050 | 95c | – |
Acetone | 493 | 502 | 0.053 | – | – | |
BODIPY/Motor | Toluene | 508 | 519 | 0.055 | 54 | 12 (3)d |
Acetone | 503 | 513 | 0.051 | 2.6 | 22 (4)d |
The excitation wavelengths for the measurements of the PL and photoisomerization QYs were 488 nm and 395 nm, respectively.
aAdapted from ref. 35.
bMeasured with a 365 nm excitation wavelength.
cAdapted from ref. 48.
dQYs of photoisomerization for the stable → metastable transformation. The numbers in parentheses are the photoisomerization QYs measured with a LED light source with the output wavelength at 535 nm and a full width at half maximum (FWHM) of ~24 nm.