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. 2022 Sep 30;12:16395. doi: 10.1038/s41598-022-20699-2

Table 2.

Oxidation reaction of various alcohols catalyzed by B-V-PIL/W.

graphic file with name 41598_2022_20699_Figa_HTML.gif
Entry Substrate Product Time (min) Yield (%)a TONb TOFc (h−1)
1 graphic file with name 41598_2022_20699_Figb_HTML.gif graphic file with name 41598_2022_20699_Figc_HTML.gif 70 95 ± 1 8550 7307
2 graphic file with name 41598_2022_20699_Figd_HTML.gif graphic file with name 41598_2022_20699_Fige_HTML.gif 45 97 ± 2 8730 11,640
3 graphic file with name 41598_2022_20699_Figf_HTML.gif graphic file with name 41598_2022_20699_Figg_HTML.gif 65 90 ± 1 8100 7479
4 graphic file with name 41598_2022_20699_Figh_HTML.gif graphic file with name 41598_2022_20699_Figi_HTML.gif 60 90 ± 2 8100 8100
5 graphic file with name 41598_2022_20699_Figj_HTML.gif graphic file with name 41598_2022_20699_Figk_HTML.gif 70 92 ± 2 8280 7137
6 graphic file with name 41598_2022_20699_Figl_HTML.gif graphic file with name 41598_2022_20699_Figm_HTML.gif 90 90 ± 2 8100 5400
7 graphic file with name 41598_2022_20699_Fign_HTML.gif graphic file with name 41598_2022_20699_Figo_HTML.gif 90 90 ± 1 8100 5400
8 graphic file with name 41598_2022_20699_Figp_HTML.gif graphic file with name 41598_2022_20699_Figq_HTML.gif 120 89 ± 1 8010 4005
9 graphic file with name 41598_2022_20699_Figr_HTML.gif graphic file with name 41598_2022_20699_Figs_HTML.gif 150 80 ± 2 7200 2880
10 graphic file with name 41598_2022_20699_Figt_HTML.gif graphic file with name 41598_2022_20699_Figu_HTML.gif 150 75 ± 1 6750 2700
11 graphic file with name 41598_2022_20699_Figv_HTML.gif graphic file with name 41598_2022_20699_Figw_HTML.gif 150 75 ± 2 6750 2700
12 graphic file with name 41598_2022_20699_Figx_HTML.gif graphic file with name 41598_2022_20699_Figy_HTML.gif 130 78 ± 2 7020 3235
13 graphic file with name 41598_2022_20699_Figz_HTML.gif graphic file with name 41598_2022_20699_Figaa_HTML.gif 120 78 ± 1 7020 3510
14 graphic file with name 41598_2022_20699_Figab_HTML.gif graphic file with name 41598_2022_20699_Figac_HTML.gif 150 75 ± 2 6750 2700
15 graphic file with name 41598_2022_20699_Figad_HTML.gif graphic file with name 41598_2022_20699_Figae_HTML.gif 160 75 ± 2 6750 2537

Reaction condition: alcohol (1 mmol), H2O2 30% (1 mmol), B-V-PIL/W 40 mg in H2O/EtOH (2/1) at 70 °C.

aIsolated yield.

bTON=Mol of produced aldehydeMol of HPA on the catalyst.

cTOF=TONTime(h)36,37.