Table 2.
Oxidation reaction of various alcohols catalyzed by B-V-PIL/W.
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Entry | Substrate | Product | Time (min) | Yield (%)a | TONb | TOFc (h−1) |
1 |
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70 | 95 ± 1 | 8550 | 7307 |
2 |
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45 | 97 ± 2 | 8730 | 11,640 |
3 |
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65 | 90 ± 1 | 8100 | 7479 |
4 |
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60 | 90 ± 2 | 8100 | 8100 |
5 |
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70 | 92 ± 2 | 8280 | 7137 |
6 |
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90 | 90 ± 2 | 8100 | 5400 |
7 |
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90 | 90 ± 1 | 8100 | 5400 |
8 |
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120 | 89 ± 1 | 8010 | 4005 |
9 |
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150 | 80 ± 2 | 7200 | 2880 |
10 |
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150 | 75 ± 1 | 6750 | 2700 |
11 |
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150 | 75 ± 2 | 6750 | 2700 |
12 |
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130 | 78 ± 2 | 7020 | 3235 |
13 |
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120 | 78 ± 1 | 7020 | 3510 |
14 |
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150 | 75 ± 2 | 6750 | 2700 |
15 |
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160 | 75 ± 2 | 6750 | 2537 |