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. 2022 Oct 3;5(6):e766. doi: 10.1002/hsr2.766

Table 2.

Name, chemical formula, and chemical structure of vitamins

Names Chemical formula Chemical structure
Vitamin B1 Thiamine/thiamin/vitamin B1 C12H17N4OS Aminopyrimidine ring linked to a thiazolium ring by a methylene bridge; methyl and hydroxyethyl side chains are present instead of a thiazole
Thiamine pyrophosphate (TPP/co‐carboxylase), thiamine hydrochloride (TH‐HC), thiamine mononitrate (TH‐MN)
Vitamin B3

Vitamin B3/vitamin PP/Niacin/Nicotinic acid

C6H5NO2 Derivate of pyridine with a carboxyl group at the 3‐position
Niacinamide/amide nicotinamide
Vitamin B5 Vitamin B5/pantotheic acid C9H17NO5 Combination of pantoic acid and beta‐alanine
Panthenol (pro‐vitamin B5)2; syntetic variants (panthenyl ethyl ether, panthenyl triacetate, calcium and sodium pantothenate)
Vitamin B6 Vitamin B6/Pyridoxine (PN) C8H11NO3 3‐Hydroxy‐4,5‐ hydroxymethyl‐2‐methylpyridine
Pyridoxamine (PM), pyridoxal (PL)/pyridoxine hydrochloride
Vitamin B7 Vitamin B7/Vitamin H/Biotin C10H16N203S Heterocyclic, sulfur‐containing, monocarboxylic acid with two rings (imidazolidone and tetrahydrothiophene moieties) fused together
Vitamin B12 Vitamin B12/Cobalamin C63H88CON14014P Planar group containing a corrin ring cetered by a cobalt ion and a nucleotide set
Cyanocobalamin (the most stable; used in pharmaceuticals), hydroxocobalamin, adenosylcobalamin (active), methylcobalamin (active)
Vitamin C Vitamin C/(l‐)Ascorbic acid (AA)/Ascorbate C6H806 2‐Oxo‐l‐theo‐hexono‐4‐lactone‐2,3‐enediol
Dehydroascorbate (DHA), d‐arabo‐ascorbic acid, l‐arabo–ascorbic acid
Vitamin A Vitamin A/Retinoids C20H30O (retinol), C20H28O (retinal), C20H28O2 (retinoid acid) 20‐Carbon molecule made up of a trimethylated cyclohexenyl ring, an isoprenoid side chain with four double bonds (the retinyl group), and a polar carbon–oxygen functional group
Retinol (alcohol isoform)/retinal (the aldehyde isoform)/retinoid acid (the irreversibly oxidized form of retinol; main metabolite)/carotenoids (provitamins A)/Retinyl palmitate (RP; storage form)
Vitamin D Vitamin D/secosteroids C27H44O (cholecalciferol), C28H44O (ergocalciferol), C27H44O3 (calcitriol) Compared with cholesterol, vitamin D has only three intact rings, being the A ring not rigidly fused to the B ring. In solution it may exhibit two spatial conformations: the 6‐s‐cis form, i.e., the steroid‐like shape, and the 6‐s‐trans, i.e., the extended shape
Cholecalciferol (previtamin D; vitamin D3; originated in the skin after sun exposure and found in animal meat), ergocalciferol (vitamin D2; found in vegetables and plants), calcitriol (active metabolite)
Vitamin E Vitamin E/alpha tocopherol C28H48O2 Basilar structure with a head made up of a chromanol ring and a tail represented by a phytyl side chain, attached at the 2‐position
Beta tocopherol, gamma tocopherol, delta tocopherol, tocotrienols
Vitamin K Vitamin K/phytonadione C28H48O2 Common 2‐methyl‐1,4 naftoquinone core, called menadione, and a phytyl side chain at the 3‐position. This side chain, which is an isoprenoid structure, may display different lengths and degrees of saturation depending on the specific isoform
Phylloquinone, menaquinone