[Ni(NCS)2(C6H7N)4]·2C2H6O	F(000) = 1352
Mr = 639.51	Dx = 1.248 Mg m−3
Monoclinic, C2/c	Cu Kα radiation, λ = 1.54184 Å
a = 18.5763 (1) Å	Cell parameters from 28027 reflections
b = 11.6179 (1) Å	θ = 4.5–79.4°
c = 15.8998 (1) Å	µ = 2.24 mm−1
β = 97.448 (1)°	T = 100 K
V = 3402.51 (4) Å3	Block, light purple
Z = 4	0.2 × 0.1 × 0.05 mm