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a) The structure of Fe2(dobdc) viewed along the [001] plane; orange, red and grey correspond to Fe, O, and C atoms. b) Gas sorption isotherms for Fe2(dobdc); blue corresponds to N2 at 298 K, whilst yellow, purple and red correspond to O2 at 211 K, 226 K and 298 K, respectively. Desorption isotherm is represented by open circles. Reprinted (adapted) with permission from J. Am. Chem. Soc. 2011, 133(37), 14814–14822. Copyright 2021 American Chemical Society.
