Table 2.

Summary data for MOFs for potential O₂ separation reported in the literature.

Metal–organic frameworks	Surface area [m2 g−1]		O2 adsorption [mmol g−1]	Pressure [bar]	Heat of adsorption, Qst [kJ mol−1]	T [K]	Ref.
	BET	Langmuir
Cd(bpndc)(4,4′‐bpy)	–	–	6.7	1	–	90	[48]
Co2(OH)2(BBTA)	1360	–	1.2	1	45	298	[25]
Co2Cl2(BBTA)	1280	–	≈ 0.26	1	19	298	[25]
Co‐BTTri	1595	1853	4.8	1	34	195	[24, 25]
Co‐BDTriP	1332	1517	4.8	1	47	195	[24, 25]
Co‐MOF‐74	–	1417	18	0.015 P/P 0	–	77	[49]
Co‐MOF‐74 Composite	1008	1150	4.8	1.2	19	204	[46]
Cr3(BTC)2	1810	2040	0.73	0.21	–	298	[22]
Cr3(BTC)2	1403	–	4.46	1	–	298	[50]
Cr‐BTT	2030	2300	2.5	1	65	298	[23]
Cu(BDT)	200	–	14	1.0 P/P 0		77	[51]
Cu(BDTri)L (L=DMF)	–	1160	17.8	0.2	–	77	[52]
Cu(BDTri)L (L=DEF)	–	240	15.9	0.2	–	77	[52]
Cu3(BTC)2	1206	–	0.2	1	–	298	[50]
Cu3(BTC)2	–	2141	25.8	0.015 P/P 0	–	77	[49]
Cu‐BTC	–	2237	0.3	1	10.7	298	[53]
Cu‐BTC Composite	1143	–	0.34	1	15.3	298	[47]
Fe‐BTTri	1630	1930	5.9	1	51	195	[19, 54]
Fe‐MOF‐74	1360	1535	5.33	0.21	41	226	[18]
Mg3(NDC)3	190	–	3.5	1.0 P/P 0	–	77	[55]
MIL‐100 (Fe)	–	1900	0.25	1	8.5	298	[56]
MIL‐100 (Sc)	–	1635	0.28	1	15.1	298	[56]
MIL‐101 (Cr) Composite	264	424	2.0	1	–	298	[57]
MIL‐101 (Ti)	2970	4440	0.85	9x10−4	–	298	[58]
MOF‐177	3100	≈4300	0.18	1	–	298	[21, 59]
Ni2(cyclam)2(mtb)	141	154	1.2	0.196	–	77	[60]
Ni‐MOF‐74	–	1234	15	0.015 P/P 0	–	77	[49]
PCN‐13	150	–	3.0	1.0 P/P0  P/P 0	–	77	[30]
PCN‐17	820	–	9.3	1.0 P/P 0		77	[31]
PCN‐224FeII	2901	–	2.4	1	34	195	[61]
UMCM‐1	4100	6500	0.23	0.96	4.9	298	[20]
Zn(TCNQ‐TCNQ)bpy	–	–	12.0	1.0 P/P 0	–	77	[29]
K0.82Fe2(bdp)3	–	1700	0.53	1	–	298	[28]
			1.43	1	–	453	[28]
K1.09Fe2(bdp)3	–	750	0.68	1	–	298	[28]
			1.32	1	–	473	[28]
K1.88Fe2(bdp)3	–	70	0.87	1	–	298	[28]
			1.64	1	–	473	[28]
K2.07Fe2(bpeb)3	–	600	0.65	1	–	298	[28]
			2.3	1	–	453	[28]