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. Author manuscript; available in PMC: 2023 Jul 14.
Published in final edited form as: Chem. 2022 Jul 1;8(7):1805–1821. doi: 10.1016/j.chempr.2022.06.005

Scheme 5. C─Halogen and C─S Bond Activation.

Scheme 5.

(A) Alkylation of secondary and tertiary alkyl chlorides

(B) Defluorinative cross-coupling by Ni/Ti cocatalysts

(C) Boration of alkyl halides and aryl bromides

(D) Reductive α-desulfonylation