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. 2022 Oct 7;8(40):eadd1267. doi: 10.1126/sciadv.add1267

Fig. 6. Substrate scope of the oxidative transformation of diols and primary alcohol into nitriles.

Fig. 6.

Reaction conditions A: 1,2-diols (0.20 mmol), Fe-N3/NC-1100 (20 mg, 0.93 mmol %), NH3·H2O (26.5 wt %, 400 μl), toluene (1.5 ml), O2 (1 bar), 25°C, and 24 hours. Reaction conditions B: 1,2-diols (0.20 mmol), Fe-N3/NC-1100 (20 mg, 0.93 mmol %), NH3·H2O (26.5 wt %, 400 μl), toluene (1.5 ml), O2 (1 bar), 120°C, and 16 hours. Reaction conditions C: primary alcohols (0.20 mmol), Fe-N3/NC-1100 (20 mg, 0.93 mmol %), NH3·H2O (26.5 wt %, 400 μl), toluene (1.5 ml), O2 (1 bar), 120°C, and 24 hours.