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. 2022 Sep 21;144(39):17929–17938. doi: 10.1021/jacs.2c06921

Figure 6.

Figure 6

(a) Plot showing the change in concentration of carbonate linkages (−OC(O)O−) in both PPC and PC against time using catalyst 1, at 55 °C, with an exponential fit to the data allowing for the determination of the pseudo first-order rate coefficient. (b) Eyring analysis, i.e., a plot of ln(kb/T) vs 1/T, for the decomposition of PPC into PC using catalyst 1. Where kb = kobs/[1] and kobs is the gradient of the plot of ln[PPC]t/[PPC]0 vs time (s).