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. 2022 Aug 4;61(38):e202207279. doi: 10.1002/anie.202207279

Table 1.

Overview on the reports that discuss the effect of adsorbed oxyanions on the OER in detail. Sorted chronologically by the year of publication.

(Pre)catalyst phase[a]

Adsorbed oxyanion

Comments

Ref.

Co3O4

SO4 2−

DFT shows that *OH/*OOH scaling relations can be broken through adsorption

[14]

CoNiFeOx

SO4 2−

[14]

NiSe2

SeO4 2−

First example of in‐situ Raman investigation and addition of oxyanion to the electrolyte

[15]

Ni(OH)2

(S/Se)O4 2−

[15]

Cu(OH)2

SeO4 2−

[15]

Co(OH)2

SeO4 2−

[15]

NiS2

SO4 2−

[15]

NiFeOOH

PO4 3−

First non‐chalcogenide oxyanion

[46]

CoFeMoO x /MoS x /SO4 2−

SO4 2−

RuFeOx

SO4 2−

Infrared spectroscopy identifies interaction with *OOH intermediate

[17]

NiFeOOH

SO4 2−/CrO4 2−/HCO3

First report on non‐chalcogenate adsorbed oxyanions

[16]

NiFe‐LDH

SO4 2−

Chloride oxidation suppression through sulfate addition

[49]

ZnIn2S4

SO4 2−

Photocatalytic OER

[53]

MoNiFeOOH

MoO4 2−

Time‐resolved tracking of re‐adsorption after leaching

[39]

NiFeS

SO4 2−

[54]

Co(Zn)OOH

SO4 2−

[55]

FeNiOOH

PO4 3−

Effect of adsorption on d‐band center is analyzed by DFT

[47]

Ni3S2

SO4 2−

[48]

NiOOH

(P/S/Se)Ox

First application for methanol oxidation, the oxyanions facilitate methanol and hydroxide adsorption

[18]

[a] For the precise stoichiometry and structure of the catalytic phases as well as reconstruction details, the referenced reports must be consulted.