Table 1.
(Pre)catalyst phase[a] |
Adsorbed oxyanion |
Comments |
Ref. |
---|---|---|---|
Co3O4 |
SO4 2− |
DFT shows that *OH/*OOH scaling relations can be broken through adsorption |
|
CoNiFeOx |
SO4 2− |
|
|
NiSe2 |
SeO4 2− |
First example of in‐situ Raman investigation and addition of oxyanion to the electrolyte |
|
Ni(OH)2 |
(S/Se)O4 2− |
|
|
Cu(OH)2 |
SeO4 2− |
|
|
Co(OH)2 |
SeO4 2− |
|
|
NiS2 |
SO4 2− |
|
|
NiFeOOH |
PO4 3− |
First non‐chalcogenide oxyanion |
|
CoFeMoO x /MoS x /SO4 2− |
SO4 2− |
|
|
RuFeOx |
SO4 2− |
Infrared spectroscopy identifies interaction with *OOH intermediate |
|
NiFeOOH |
SO4 2−/CrO4 2−/HCO3 − |
First report on non‐chalcogenate adsorbed oxyanions |
|
NiFe‐LDH |
SO4 2− |
Chloride oxidation suppression through sulfate addition |
|
ZnIn2S4 |
SO4 2− |
Photocatalytic OER |
|
MoNiFeOOH |
MoO4 2− |
Time‐resolved tracking of re‐adsorption after leaching |
|
NiFeS |
SO4 2− |
|
|
Co(Zn)OOH |
SO4 2− |
|
|
FeNiOOH |
PO4 3− |
Effect of adsorption on d‐band center is analyzed by DFT |
|
Ni3S2 |
SO4 2− |
“ |
|
NiOOH |
(P/S/Se)Ox |
First application for methanol oxidation, the oxyanions facilitate methanol and hydroxide adsorption |
[a] For the precise stoichiometry and structure of the catalytic phases as well as reconstruction details, the referenced reports must be consulted.