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. 2022 Sep 22;29(50):75223–75247. doi: 10.1007/s11356-022-23045-1

Table 7.

Cosmetics removal by chemical methods

Compound Material Initial concentration Removal (%, time) Major mechanism Ref
Methylparaben (MP), ethylparaben (EP), propylparaben (PP), butylparaben (BP) Ozone - 94.85–99.22% of all four simultaneously after 15 min

Ozonation and UV irradiation

(O3/UV/TiO2/H2O)

Cuerda-Correa et al. (2016)
Methylparaben (MP), ethylparaben (EP), propylparaben (PP), butylparaben (BP), chemical oxygen demand COD Ozone

70 mg H2O2/L,

8 mg O3/L

All parabens 100% after 120 min, COD 70% O3/H2O2 Gmurek et al. (2019)
Methylparaben (MP), ethylparaben (EP), propylparaben (PP), butylparaben (BP), chemical oxygen demand COD

TiO2-Pt,

TiO2-Pd,

TiO2-Ag

Ozone

45 mg O3 All parabens 100% after 120 min, COD 41–49%

O3/UVA/TiO2-Pt

O3/UVA/TiO2-Pd

O3/UVA/TiO2-Ag

Gmurek et al. (2019)
Chemical oxygen demand COD Light/Fe0/H2O2

1000 mg/L Fe0

2280 mg/L H2O2

70% after 120 min just by the combined process, then 97.7% after SBR

Combined light/Fe0/H2O2 and sequencing

batch reactor (SBR)

Muszyński et al. (2019)
Total organic carbon (TOC) H2O2/Fe3O4/Fe2O3/Fe0

500 mg/L Fe3O4

500 mg/L Fe2O3

1000 mg/L Fe0

56.2% after 120 min UV/H2O2/Fe3O4/Fe2O3/Fe0 Bogacki et al. (2020)
Total organic carbon (TOC), chemical oxygen demand (COD) Metallurgical waste, H2O2

MW 8.0 g/L,

H2O2 0.05 g/L

TOC 75% after 6 min

COD 99% after 6 min

heterogeneous photo Fenton-Like

degradation treatment

de Andrade et al. (2020)

Brilliant Green

Methylene Blue

rGO/Ag2O Nanocomposite

30 mg in 15 mL MB or BG solution

(10 ppm)

BG 75%, after 70 min

MB 90%, after 150 min

photocatalytic reduction Iqbal et al. (2021)