Table 1. Summary of the Ln(TrensalR) Complexesa.
ligand | complex |
---|---|
Trensal | [Dy(Trensal)] (1)b |
[Nd(Trensal)(H2O)] (7)b | |
[Nd(Trensal)]·ACN (8·ACN)b | |
Trensalo-Cl | [Dy(Trensalo-Cl)] (2) |
[Nd(Trensalo-Cl)(DMF)]·DMF (11·DMF) | |
Trensalo-tBu | [Dy(Trensalo-tBu)]·acetone (3·acetone) |
[Nd(Trensalo-tBu)]·DMF (10·DMF) | |
Trensalp-I | [Dy(Trensalp-I)]·3DMF (4·3DMF) |
[Nd(Trensalp-I)(DMF)(H2O)]·DMF (9·DMF) | |
Trensalp-oMe | [Dy(Trensalp-OMe)] (5) |
[Nd(Trensalp-OMe)(H2O)] (13) | |
Trensalp-Cl | [Dy(Trensalp-Cl)] (6) |
[Nd(Trensalp-Cl)(DMF)(H2O)] (12) |
The synthesis was performed in acetone.
The synthesis was performed in acetonitrile.