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. 2022 Sep 30;61(40):16110–16121. doi: 10.1021/acs.inorgchem.2c02619

Table 1. Summary of the Ln(TrensalR) Complexesa.

ligand complex
Trensal [Dy(Trensal)] (1)b
  [Nd(Trensal)(H2O)] (7)b
  [Nd(Trensal)]·ACN (8·ACN)b
Trensalo-Cl [Dy(Trensalo-Cl)] (2)
  [Nd(Trensalo-Cl)(DMF)]·DMF (11·DMF)
Trensalo-tBu [Dy(Trensalo-tBu)]·acetone (3·acetone)
  [Nd(Trensalo-tBu)]·DMF (10·DMF)
Trensalp-I [Dy(Trensalp-I)]·3DMF (4·3DMF)
  [Nd(Trensalp-I)(DMF)(H2O)]·DMF (9·DMF)
Trensalp-oMe [Dy(Trensalp-OMe)] (5)
  [Nd(Trensalp-OMe)(H2O)] (13)
Trensalp-Cl [Dy(Trensalp-Cl)] (6)
  [Nd(Trensalp-Cl)(DMF)(H2O)] (12)
a

The synthesis was performed in acetone.

b

The synthesis was performed in acetonitrile.