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. 2022 Sep 22;7(40):36009–36016. doi: 10.1021/acsomega.2c05290

Table 1. Parameters of the Langmuir–Hinshelwood Mechanism in Figure 4 Fitted with Equation 1 and Half-Life (τ1/2) for 300 ppbv O3(g) and Reactive Uptake Coefficient (γO3RH) from Equation 3.

RH (%) kcat+O3,maxRH (s–1) KO3(cm3 molecules–1) r2 τ1/2 (h) γO3RH
90 1.242 (±0.105) × 10–2 2.106 (±0.477) × 10–16 0.975 10.3 1.58 × 10–5
70 7.210 (±0.534) × 10–3 2.507 (±0.536) × 10–16 0.976 14.9 1.10 × 10–5
30 5.751 (±1.334) × 10–3 1.136 (±0.606) × 10–16 0.938 41.1 3.96 × 10–6
0 2.334 (±0.254) × 10–3 1.792 (±0.549) × 10–16 0.976 64.3 2.53 × 10–6